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N′-[4-(Dimethylamino)benzylidene]-3-hydroxy-2-naphthohydrazide
The title compound, C(20)H(19)N(3)O(2), was obtained by the condensation of 4-(dimethylamino)benzaldehyde with 3-hydroxy-2-naphthohydrazide. The molecule is approximately planar, with an intramolecular N—H⋯O hydrogen bond involving the imino H atom and the hydroxy O atom. The dihedral angle bet...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969016/ https://www.ncbi.nlm.nih.gov/pubmed/21582600 http://dx.doi.org/10.1107/S160053680900960X |
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author | Huang, Hai-Tao |
author_facet | Huang, Hai-Tao |
author_sort | Huang, Hai-Tao |
collection | PubMed |
description | The title compound, C(20)H(19)N(3)O(2), was obtained by the condensation of 4-(dimethylamino)benzaldehyde with 3-hydroxy-2-naphthohydrazide. The molecule is approximately planar, with an intramolecular N—H⋯O hydrogen bond involving the imino H atom and the hydroxy O atom. The dihedral angle between the benzene ring and the naphthyl mean plane is 2.72 (13)°. In the crystal structure, symmetry-related molecules are linked by intermolecular O—H⋯O hydrogen bonds, forming chains propagating in the c-axis direction. |
format | Text |
id | pubmed-2969016 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29690162010-12-30 N′-[4-(Dimethylamino)benzylidene]-3-hydroxy-2-naphthohydrazide Huang, Hai-Tao Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(19)N(3)O(2), was obtained by the condensation of 4-(dimethylamino)benzaldehyde with 3-hydroxy-2-naphthohydrazide. The molecule is approximately planar, with an intramolecular N—H⋯O hydrogen bond involving the imino H atom and the hydroxy O atom. The dihedral angle between the benzene ring and the naphthyl mean plane is 2.72 (13)°. In the crystal structure, symmetry-related molecules are linked by intermolecular O—H⋯O hydrogen bonds, forming chains propagating in the c-axis direction. International Union of Crystallography 2009-03-28 /pmc/articles/PMC2969016/ /pubmed/21582600 http://dx.doi.org/10.1107/S160053680900960X Text en © Hai-Tao Huang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Huang, Hai-Tao N′-[4-(Dimethylamino)benzylidene]-3-hydroxy-2-naphthohydrazide |
title |
N′-[4-(Dimethylamino)benzylidene]-3-hydroxy-2-naphthohydrazide |
title_full |
N′-[4-(Dimethylamino)benzylidene]-3-hydroxy-2-naphthohydrazide |
title_fullStr |
N′-[4-(Dimethylamino)benzylidene]-3-hydroxy-2-naphthohydrazide |
title_full_unstemmed |
N′-[4-(Dimethylamino)benzylidene]-3-hydroxy-2-naphthohydrazide |
title_short |
N′-[4-(Dimethylamino)benzylidene]-3-hydroxy-2-naphthohydrazide |
title_sort | n′-[4-(dimethylamino)benzylidene]-3-hydroxy-2-naphthohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969016/ https://www.ncbi.nlm.nih.gov/pubmed/21582600 http://dx.doi.org/10.1107/S160053680900960X |
work_keys_str_mv | AT huanghaitao n4dimethylaminobenzylidene3hydroxy2naphthohydrazide |