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Phyllo-poly[[μ(2)-1,4-bis(cyclohexylsulfanylmethyl)benzene-κ(2) S:S′](μ(2)-nitrato-κ(2) O:O′)silver(I)]
The title compound, [Ag(NO(3))(C(20)H(30)S(2))](n), was synthesized by the reaction of silver nitrate and 1,4-bis(cyclohexylthiomethyl)benzene (bctmb) in acetonitrile. The coordination polymer exhibits a two-dimensional layer structure. The layers are wave-like and parallel to the crystallograp...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969017/ https://www.ncbi.nlm.nih.gov/pubmed/21582336 http://dx.doi.org/10.1107/S1600536809007910 |
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author | Kim, Tae Ho Shin, Yong Woon Park, Ki-Min Kim, Jineun |
author_facet | Kim, Tae Ho Shin, Yong Woon Park, Ki-Min Kim, Jineun |
author_sort | Kim, Tae Ho |
collection | PubMed |
description | The title compound, [Ag(NO(3))(C(20)H(30)S(2))](n), was synthesized by the reaction of silver nitrate and 1,4-bis(cyclohexylthiomethyl)benzene (bctmb) in acetonitrile. The coordination polymer exhibits a two-dimensional layer structure. The layers are wave-like and parallel to the crystallographic ac plane; Ag(I) ions are linked by the bctmb ligands and nitrate anions along the crystallographic a and c directions, respectively. In addition, the crystal structure is stabilized by C—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2969017 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29690172010-12-30 Phyllo-poly[[μ(2)-1,4-bis(cyclohexylsulfanylmethyl)benzene-κ(2) S:S′](μ(2)-nitrato-κ(2) O:O′)silver(I)] Kim, Tae Ho Shin, Yong Woon Park, Ki-Min Kim, Jineun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ag(NO(3))(C(20)H(30)S(2))](n), was synthesized by the reaction of silver nitrate and 1,4-bis(cyclohexylthiomethyl)benzene (bctmb) in acetonitrile. The coordination polymer exhibits a two-dimensional layer structure. The layers are wave-like and parallel to the crystallographic ac plane; Ag(I) ions are linked by the bctmb ligands and nitrate anions along the crystallographic a and c directions, respectively. In addition, the crystal structure is stabilized by C—H⋯O hydrogen bonds. International Union of Crystallography 2009-03-11 /pmc/articles/PMC2969017/ /pubmed/21582336 http://dx.doi.org/10.1107/S1600536809007910 Text en © Kim et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kim, Tae Ho Shin, Yong Woon Park, Ki-Min Kim, Jineun Phyllo-poly[[μ(2)-1,4-bis(cyclohexylsulfanylmethyl)benzene-κ(2) S:S′](μ(2)-nitrato-κ(2) O:O′)silver(I)] |
title | Phyllo-poly[[μ(2)-1,4-bis(cyclohexylsulfanylmethyl)benzene-κ(2)
S:S′](μ(2)-nitrato-κ(2)
O:O′)silver(I)] |
title_full | Phyllo-poly[[μ(2)-1,4-bis(cyclohexylsulfanylmethyl)benzene-κ(2)
S:S′](μ(2)-nitrato-κ(2)
O:O′)silver(I)] |
title_fullStr | Phyllo-poly[[μ(2)-1,4-bis(cyclohexylsulfanylmethyl)benzene-κ(2)
S:S′](μ(2)-nitrato-κ(2)
O:O′)silver(I)] |
title_full_unstemmed | Phyllo-poly[[μ(2)-1,4-bis(cyclohexylsulfanylmethyl)benzene-κ(2)
S:S′](μ(2)-nitrato-κ(2)
O:O′)silver(I)] |
title_short | Phyllo-poly[[μ(2)-1,4-bis(cyclohexylsulfanylmethyl)benzene-κ(2)
S:S′](μ(2)-nitrato-κ(2)
O:O′)silver(I)] |
title_sort | phyllo-poly[[μ(2)-1,4-bis(cyclohexylsulfanylmethyl)benzene-κ(2)
s:s′](μ(2)-nitrato-κ(2)
o:o′)silver(i)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969017/ https://www.ncbi.nlm.nih.gov/pubmed/21582336 http://dx.doi.org/10.1107/S1600536809007910 |
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