Bis{2-[6-(1H-benzimidazol-2-yl-κN (3))-2-pyridyl-κN]benzimidazolato-κN}manganese(II)

In the title compound, [Mn(C(19)H(12)N(5))(2)], each Mn(II) atom lies on a position of site symmetry 222 and has a distorted octa­hedral coordination geometry made up from six N atoms of two tridentate 2-[6-(1H-benzimidazol-2-yl)-2-pyrid­yl]benz­imidazolate ligands. The complex mol­ecules are linked...

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Detalles Bibliográficos
Autores principales: Bai, Xian-Qun, Zhang, Shu-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969020/
https://www.ncbi.nlm.nih.gov/pubmed/21582344
http://dx.doi.org/10.1107/S1600536809008411
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author Bai, Xian-Qun
Zhang, Shu-Hua
author_facet Bai, Xian-Qun
Zhang, Shu-Hua
author_sort Bai, Xian-Qun
collection PubMed
description In the title compound, [Mn(C(19)H(12)N(5))(2)], each Mn(II) atom lies on a position of site symmetry 222 and has a distorted octa­hedral coordination geometry made up from six N atoms of two tridentate 2-[6-(1H-benzimidazol-2-yl)-2-pyrid­yl]benz­imidazolate ligands. The complex mol­ecules are linked into layers parallel to (001) by N—H⋯N hydrogen bonds, with the H atoms disordered over four symmetry-equivalent non-coordinated N atoms.
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spelling pubmed-29690202010-12-30 Bis{2-[6-(1H-benzimidazol-2-yl-κN (3))-2-pyridyl-κN]benzimidazolato-κN}manganese(II) Bai, Xian-Qun Zhang, Shu-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(19)H(12)N(5))(2)], each Mn(II) atom lies on a position of site symmetry 222 and has a distorted octa­hedral coordination geometry made up from six N atoms of two tridentate 2-[6-(1H-benzimidazol-2-yl)-2-pyrid­yl]benz­imidazolate ligands. The complex mol­ecules are linked into layers parallel to (001) by N—H⋯N hydrogen bonds, with the H atoms disordered over four symmetry-equivalent non-coordinated N atoms. International Union of Crystallography 2009-03-14 /pmc/articles/PMC2969020/ /pubmed/21582344 http://dx.doi.org/10.1107/S1600536809008411 Text en © Bai and Zhang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bai, Xian-Qun
Zhang, Shu-Hua
Bis{2-[6-(1H-benzimidazol-2-yl-κN (3))-2-pyridyl-κN]benzimidazolato-κN}manganese(II)
title Bis{2-[6-(1H-benzimidazol-2-yl-κN (3))-2-pyridyl-κN]benzimidazolato-κN}manganese(II)
title_full Bis{2-[6-(1H-benzimidazol-2-yl-κN (3))-2-pyridyl-κN]benzimidazolato-κN}manganese(II)
title_fullStr Bis{2-[6-(1H-benzimidazol-2-yl-κN (3))-2-pyridyl-κN]benzimidazolato-κN}manganese(II)
title_full_unstemmed Bis{2-[6-(1H-benzimidazol-2-yl-κN (3))-2-pyridyl-κN]benzimidazolato-κN}manganese(II)
title_short Bis{2-[6-(1H-benzimidazol-2-yl-κN (3))-2-pyridyl-κN]benzimidazolato-κN}manganese(II)
title_sort bis{2-[6-(1h-benzimidazol-2-yl-κn (3))-2-pyridyl-κn]benzimidazolato-κn}manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969020/
https://www.ncbi.nlm.nih.gov/pubmed/21582344
http://dx.doi.org/10.1107/S1600536809008411
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AT zhangshuhua bis261hbenzimidazol2ylkn32pyridylknbenzimidazolatoknmanganeseii

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