3-Mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 4-chloro­benzoate

The title compound, C(24)H(23)ClO(4), is a potent insecticide and miticide. The five-membered cyclo­pentane ring displays an envelope conformation with the atom at the flap position 0.611 (2) Å out of the mean plane formed by the other four atoms. The furan ring makes dihedral angles of 71.3 (2) and...

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Detalles Bibliográficos
Autores principales: Ji, Ming-Hua, Xia, Min, Zhu, Guo-Nian, Zhao, Jin-Hao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969026/
https://www.ncbi.nlm.nih.gov/pubmed/21582443
http://dx.doi.org/10.1107/S1600536809006503
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author Ji, Ming-Hua
Xia, Min
Zhu, Guo-Nian
Zhao, Jin-Hao
author_facet Ji, Ming-Hua
Xia, Min
Zhu, Guo-Nian
Zhao, Jin-Hao
author_sort Ji, Ming-Hua
collection PubMed
description The title compound, C(24)H(23)ClO(4), is a potent insecticide and miticide. The five-membered cyclo­pentane ring displays an envelope conformation with the atom at the flap position 0.611 (2) Å out of the mean plane formed by the other four atoms. The furan ring makes dihedral angles of 71.3 (2) and 81.9 (2)°, respectively, with the 2,4,6-trimethyl­phenyl and 4-chloro­phenyl rings. The dihedral angle between the two benzene rings is 76.6 (1)°. In the crystal, mol­ecules are linked through weak inter­molecular C—H⋯O hydrogen bonds, forming chains running along the c axis.
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spelling pubmed-29690262010-12-30 3-Mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 4-chloro­benzoate Ji, Ming-Hua Xia, Min Zhu, Guo-Nian Zhao, Jin-Hao Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(24)H(23)ClO(4), is a potent insecticide and miticide. The five-membered cyclo­pentane ring displays an envelope conformation with the atom at the flap position 0.611 (2) Å out of the mean plane formed by the other four atoms. The furan ring makes dihedral angles of 71.3 (2) and 81.9 (2)°, respectively, with the 2,4,6-trimethyl­phenyl and 4-chloro­phenyl rings. The dihedral angle between the two benzene rings is 76.6 (1)°. In the crystal, mol­ecules are linked through weak inter­molecular C—H⋯O hydrogen bonds, forming chains running along the c axis. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2969026/ /pubmed/21582443 http://dx.doi.org/10.1107/S1600536809006503 Text en © Ji et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ji, Ming-Hua
Xia, Min
Zhu, Guo-Nian
Zhao, Jin-Hao
3-Mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 4-chloro­benzoate
title 3-Mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 4-chloro­benzoate
title_full 3-Mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 4-chloro­benzoate
title_fullStr 3-Mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 4-chloro­benzoate
title_full_unstemmed 3-Mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 4-chloro­benzoate
title_short 3-Mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 4-chloro­benzoate
title_sort 3-mesityl-2-oxo-1-oxaspiro­[4.4]non-3-en-4-yl 4-chloro­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969026/
https://www.ncbi.nlm.nih.gov/pubmed/21582443
http://dx.doi.org/10.1107/S1600536809006503
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