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(±)-2-Oxocyclopentaneacetic acid: catemeric hydrogen bonding in a γ-keto acid
The title racemate, C(7)H(10)O(3), aggregates in the solid as acid-to-ketone hydrogen-bonding catemers [O⋯O = 2.7050 (13) Å and O—H⋯O = 166.1 (17)°] having glide-related components. Four such heterochiral chains, paired centrosymmetrically about ([Image: see text], [Image: see text], [Image: see tex...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969029/ https://www.ncbi.nlm.nih.gov/pubmed/21582637 http://dx.doi.org/10.1107/S1600536809010708 |
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author | Efthimiopoulos, Georgia Papadakis, Markos M. Thompson, Hugh W. Lalancette, Roger A. |
author_facet | Efthimiopoulos, Georgia Papadakis, Markos M. Thompson, Hugh W. Lalancette, Roger A. |
author_sort | Efthimiopoulos, Georgia |
collection | PubMed |
description | The title racemate, C(7)H(10)O(3), aggregates in the solid as acid-to-ketone hydrogen-bonding catemers [O⋯O = 2.7050 (13) Å and O—H⋯O = 166.1 (17)°] having glide-related components. Four such heterochiral chains, paired centrosymmetrically about ([Image: see text], [Image: see text], [Image: see text]) in the cell, proceed through the cell in the 010 direction, with alignment with respect to the c axis of ++−−. |
format | Text |
id | pubmed-2969029 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29690292010-12-30 (±)-2-Oxocyclopentaneacetic acid: catemeric hydrogen bonding in a γ-keto acid Efthimiopoulos, Georgia Papadakis, Markos M. Thompson, Hugh W. Lalancette, Roger A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title racemate, C(7)H(10)O(3), aggregates in the solid as acid-to-ketone hydrogen-bonding catemers [O⋯O = 2.7050 (13) Å and O—H⋯O = 166.1 (17)°] having glide-related components. Four such heterochiral chains, paired centrosymmetrically about ([Image: see text], [Image: see text], [Image: see text]) in the cell, proceed through the cell in the 010 direction, with alignment with respect to the c axis of ++−−. International Union of Crystallography 2009-03-31 /pmc/articles/PMC2969029/ /pubmed/21582637 http://dx.doi.org/10.1107/S1600536809010708 Text en © Efthimiopoulos et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Efthimiopoulos, Georgia Papadakis, Markos M. Thompson, Hugh W. Lalancette, Roger A. (±)-2-Oxocyclopentaneacetic acid: catemeric hydrogen bonding in a γ-keto acid |
title | (±)-2-Oxocyclopentaneacetic acid: catemeric hydrogen bonding in a γ-keto acid |
title_full | (±)-2-Oxocyclopentaneacetic acid: catemeric hydrogen bonding in a γ-keto acid |
title_fullStr | (±)-2-Oxocyclopentaneacetic acid: catemeric hydrogen bonding in a γ-keto acid |
title_full_unstemmed | (±)-2-Oxocyclopentaneacetic acid: catemeric hydrogen bonding in a γ-keto acid |
title_short | (±)-2-Oxocyclopentaneacetic acid: catemeric hydrogen bonding in a γ-keto acid |
title_sort | (±)-2-oxocyclopentaneacetic acid: catemeric hydrogen bonding in a γ-keto acid |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969029/ https://www.ncbi.nlm.nih.gov/pubmed/21582637 http://dx.doi.org/10.1107/S1600536809010708 |
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