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2-(1H-Benzoimidazol-2-yl)-6-ethoxy­phenol

The title Schiff base compound, C(15)H(14)N(2)O(2), consists of two crystallographically independent mol­ecules, A and B. Mol­ecule A is almost planar, whereas mol­ecule B is slightly twisted, the dihedral angles between the benzimidazole group and the benzene rings being 2.65 (12) and 13.17 (15)°,...

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Autores principales: Yeap, Chin Sing, Kargar, Hadi, Kia, Reza, Jamshidvand, Arezoo, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969036/
https://www.ncbi.nlm.nih.gov/pubmed/21582478
http://dx.doi.org/10.1107/S1600536809008071
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author Yeap, Chin Sing
Kargar, Hadi
Kia, Reza
Jamshidvand, Arezoo
Fun, Hoong-Kun
author_facet Yeap, Chin Sing
Kargar, Hadi
Kia, Reza
Jamshidvand, Arezoo
Fun, Hoong-Kun
author_sort Yeap, Chin Sing
collection PubMed
description The title Schiff base compound, C(15)H(14)N(2)O(2), consists of two crystallographically independent mol­ecules, A and B. Mol­ecule A is almost planar, whereas mol­ecule B is slightly twisted, the dihedral angles between the benzimidazole group and the benzene rings being 2.65 (12) and 13.17 (15)°, respectively. The methyl group of mol­ecule B is disordered over two positions, with a refined site-occupancy ratio of 0.581 (7):0.419 (7). In each mol­ecule, intra­molecular O—H⋯N hydrogen bonds generate S(6) ring motifs. In the crystal structure, both types of mol­ecules are linked via inter­molecular bifurcated N—H⋯O hydrogen bonds into one-dimensional extended chains along [010] and form R (1) (2)(5) ring motifs. The crystal structure is further stabilized by inter­molecular C—H⋯π and π–π inter­actions [centroid–centroid distances = 3.4758 (16)–3.596 (2) Å].
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spelling pubmed-29690362010-12-30 2-(1H-Benzoimidazol-2-yl)-6-ethoxy­phenol Yeap, Chin Sing Kargar, Hadi Kia, Reza Jamshidvand, Arezoo Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(15)H(14)N(2)O(2), consists of two crystallographically independent mol­ecules, A and B. Mol­ecule A is almost planar, whereas mol­ecule B is slightly twisted, the dihedral angles between the benzimidazole group and the benzene rings being 2.65 (12) and 13.17 (15)°, respectively. The methyl group of mol­ecule B is disordered over two positions, with a refined site-occupancy ratio of 0.581 (7):0.419 (7). In each mol­ecule, intra­molecular O—H⋯N hydrogen bonds generate S(6) ring motifs. In the crystal structure, both types of mol­ecules are linked via inter­molecular bifurcated N—H⋯O hydrogen bonds into one-dimensional extended chains along [010] and form R (1) (2)(5) ring motifs. The crystal structure is further stabilized by inter­molecular C—H⋯π and π–π inter­actions [centroid–centroid distances = 3.4758 (16)–3.596 (2) Å]. International Union of Crystallography 2009-03-14 /pmc/articles/PMC2969036/ /pubmed/21582478 http://dx.doi.org/10.1107/S1600536809008071 Text en © Yeap et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yeap, Chin Sing
Kargar, Hadi
Kia, Reza
Jamshidvand, Arezoo
Fun, Hoong-Kun
2-(1H-Benzoimidazol-2-yl)-6-ethoxy­phenol
title 2-(1H-Benzoimidazol-2-yl)-6-ethoxy­phenol
title_full 2-(1H-Benzoimidazol-2-yl)-6-ethoxy­phenol
title_fullStr 2-(1H-Benzoimidazol-2-yl)-6-ethoxy­phenol
title_full_unstemmed 2-(1H-Benzoimidazol-2-yl)-6-ethoxy­phenol
title_short 2-(1H-Benzoimidazol-2-yl)-6-ethoxy­phenol
title_sort 2-(1h-benzoimidazol-2-yl)-6-ethoxy­phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969036/
https://www.ncbi.nlm.nih.gov/pubmed/21582478
http://dx.doi.org/10.1107/S1600536809008071
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