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N′-(3-Bromo-5-chloro-2-hydroxy­benzyl­idene)-2-methoxy­benzohydrazide

The title compound, C(15)H(12)BrClN(2)O(3), was obtained by the condensation reaction between 3-bromo-5-chloro-2-hydroxy­benzaldehyde and 2-methoxy­benzohydrazide. The mol­ecule is essentially planar, with a dihedral angle between the two benzene rings of 4.7 (2)°, and displays an E configuration ab...

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Detalles Bibliográficos
Autor principal: Hou, Jin-Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969039/
https://www.ncbi.nlm.nih.gov/pubmed/21582569
http://dx.doi.org/10.1107/S1600536809010198
Descripción
Sumario:The title compound, C(15)H(12)BrClN(2)O(3), was obtained by the condensation reaction between 3-bromo-5-chloro-2-hydroxy­benzaldehyde and 2-methoxy­benzohydrazide. The mol­ecule is essentially planar, with a dihedral angle between the two benzene rings of 4.7 (2)°, and displays an E configuration about the C=N double bond. The mol­ecular conformation is stabilized by intramolecular O—H⋯N and N—H⋯O hydrogen bonds. In the crystal structure, mol­ecules are linked into zigzag chains running parallel to the c axis by inter­molecular C—H⋯O hydrogen bonds. The chains are further connected through aromatic π–π stacking inter­actions with centroid–centroid distances of 3.583 (4) Å.