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N′-(3-Bromo-5-chloro-2-hydroxy­benzyl­idene)-2-methoxy­benzohydrazide

The title compound, C(15)H(12)BrClN(2)O(3), was obtained by the condensation reaction between 3-bromo-5-chloro-2-hydroxy­benzaldehyde and 2-methoxy­benzohydrazide. The mol­ecule is essentially planar, with a dihedral angle between the two benzene rings of 4.7 (2)°, and displays an E configuration ab...

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Detalles Bibliográficos
Autor principal: Hou, Jin-Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969039/
https://www.ncbi.nlm.nih.gov/pubmed/21582569
http://dx.doi.org/10.1107/S1600536809010198
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author Hou, Jin-Long
author_facet Hou, Jin-Long
author_sort Hou, Jin-Long
collection PubMed
description The title compound, C(15)H(12)BrClN(2)O(3), was obtained by the condensation reaction between 3-bromo-5-chloro-2-hydroxy­benzaldehyde and 2-methoxy­benzohydrazide. The mol­ecule is essentially planar, with a dihedral angle between the two benzene rings of 4.7 (2)°, and displays an E configuration about the C=N double bond. The mol­ecular conformation is stabilized by intramolecular O—H⋯N and N—H⋯O hydrogen bonds. In the crystal structure, mol­ecules are linked into zigzag chains running parallel to the c axis by inter­molecular C—H⋯O hydrogen bonds. The chains are further connected through aromatic π–π stacking inter­actions with centroid–centroid distances of 3.583 (4) Å.
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spelling pubmed-29690392010-12-30 N′-(3-Bromo-5-chloro-2-hydroxy­benzyl­idene)-2-methoxy­benzohydrazide Hou, Jin-Long Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(12)BrClN(2)O(3), was obtained by the condensation reaction between 3-bromo-5-chloro-2-hydroxy­benzaldehyde and 2-methoxy­benzohydrazide. The mol­ecule is essentially planar, with a dihedral angle between the two benzene rings of 4.7 (2)°, and displays an E configuration about the C=N double bond. The mol­ecular conformation is stabilized by intramolecular O—H⋯N and N—H⋯O hydrogen bonds. In the crystal structure, mol­ecules are linked into zigzag chains running parallel to the c axis by inter­molecular C—H⋯O hydrogen bonds. The chains are further connected through aromatic π–π stacking inter­actions with centroid–centroid distances of 3.583 (4) Å. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2969039/ /pubmed/21582569 http://dx.doi.org/10.1107/S1600536809010198 Text en © Jin-Long Hou 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hou, Jin-Long
N′-(3-Bromo-5-chloro-2-hydroxy­benzyl­idene)-2-methoxy­benzohydrazide
title N′-(3-Bromo-5-chloro-2-hydroxy­benzyl­idene)-2-methoxy­benzohydrazide
title_full N′-(3-Bromo-5-chloro-2-hydroxy­benzyl­idene)-2-methoxy­benzohydrazide
title_fullStr N′-(3-Bromo-5-chloro-2-hydroxy­benzyl­idene)-2-methoxy­benzohydrazide
title_full_unstemmed N′-(3-Bromo-5-chloro-2-hydroxy­benzyl­idene)-2-methoxy­benzohydrazide
title_short N′-(3-Bromo-5-chloro-2-hydroxy­benzyl­idene)-2-methoxy­benzohydrazide
title_sort n′-(3-bromo-5-chloro-2-hydroxy­benzyl­idene)-2-methoxy­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969039/
https://www.ncbi.nlm.nih.gov/pubmed/21582569
http://dx.doi.org/10.1107/S1600536809010198
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