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Pyrazino[2,3-b]indolizine-10-carbonitrile

In the crystal structure of the title compound, C(11)H(6)N(4), neighbouring mol­ecules are linked into inversion dimers through pairs of weak C—H⋯N hydrogen bonds, forming an R (2) (2)(10) ring motif. The dimers forming this motif are further linked by π–π inter­actions. With respective average devi...

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Detalles Bibliográficos
Autores principales: Stefańska, Anita, Zarzeczańska, Dorota, Ossowski, Tadeusz, Sikorski, Artur
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969041/
https://www.ncbi.nlm.nih.gov/pubmed/21582499
http://dx.doi.org/10.1107/S1600536809008939
Descripción
Sumario:In the crystal structure of the title compound, C(11)H(6)N(4), neighbouring mol­ecules are linked into inversion dimers through pairs of weak C—H⋯N hydrogen bonds, forming an R (2) (2)(10) ring motif. The dimers forming this motif are further linked by π–π inter­actions. With respective average deviations from planarity of 0.004 (2) and 0.004 (1) Å, the pyrazino[2,3-β]indolizine and cyano fragment are oriented at 0.8 (1)° to each other. The mean planes of the pyrazino[2,3-b]indolizine skeleton either lie parallel or are inclined at an angle of 28.7 (2)° in the crystal.