Pyrazino[2,3-b]indolizine-10-carbonitrile

In the crystal structure of the title compound, C(11)H(6)N(4), neighbouring mol­ecules are linked into inversion dimers through pairs of weak C—H⋯N hydrogen bonds, forming an R (2) (2)(10) ring motif. The dimers forming this motif are further linked by π–π inter­actions. With respective average devi...

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Autores principales: Stefańska, Anita, Zarzeczańska, Dorota, Ossowski, Tadeusz, Sikorski, Artur
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969041/
https://www.ncbi.nlm.nih.gov/pubmed/21582499
http://dx.doi.org/10.1107/S1600536809008939
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author Stefańska, Anita
Zarzeczańska, Dorota
Ossowski, Tadeusz
Sikorski, Artur
author_facet Stefańska, Anita
Zarzeczańska, Dorota
Ossowski, Tadeusz
Sikorski, Artur
author_sort Stefańska, Anita
collection PubMed
description In the crystal structure of the title compound, C(11)H(6)N(4), neighbouring mol­ecules are linked into inversion dimers through pairs of weak C—H⋯N hydrogen bonds, forming an R (2) (2)(10) ring motif. The dimers forming this motif are further linked by π–π inter­actions. With respective average deviations from planarity of 0.004 (2) and 0.004 (1) Å, the pyrazino[2,3-β]indolizine and cyano fragment are oriented at 0.8 (1)° to each other. The mean planes of the pyrazino[2,3-b]indolizine skeleton either lie parallel or are inclined at an angle of 28.7 (2)° in the crystal.
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spelling pubmed-29690412010-12-30 Pyrazino[2,3-b]indolizine-10-carbonitrile Stefańska, Anita Zarzeczańska, Dorota Ossowski, Tadeusz Sikorski, Artur Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(11)H(6)N(4), neighbouring mol­ecules are linked into inversion dimers through pairs of weak C—H⋯N hydrogen bonds, forming an R (2) (2)(10) ring motif. The dimers forming this motif are further linked by π–π inter­actions. With respective average deviations from planarity of 0.004 (2) and 0.004 (1) Å, the pyrazino[2,3-β]indolizine and cyano fragment are oriented at 0.8 (1)° to each other. The mean planes of the pyrazino[2,3-b]indolizine skeleton either lie parallel or are inclined at an angle of 28.7 (2)° in the crystal. International Union of Crystallography 2009-03-14 /pmc/articles/PMC2969041/ /pubmed/21582499 http://dx.doi.org/10.1107/S1600536809008939 Text en © Stefańska et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Stefańska, Anita
Zarzeczańska, Dorota
Ossowski, Tadeusz
Sikorski, Artur
Pyrazino[2,3-b]indolizine-10-carbonitrile
title Pyrazino[2,3-b]indolizine-10-carbonitrile
title_full Pyrazino[2,3-b]indolizine-10-carbonitrile
title_fullStr Pyrazino[2,3-b]indolizine-10-carbonitrile
title_full_unstemmed Pyrazino[2,3-b]indolizine-10-carbonitrile
title_short Pyrazino[2,3-b]indolizine-10-carbonitrile
title_sort pyrazino[2,3-b]indolizine-10-carbonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969041/
https://www.ncbi.nlm.nih.gov/pubmed/21582499
http://dx.doi.org/10.1107/S1600536809008939
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AT zarzeczanskadorota pyrazino23bindolizine10carbonitrile
AT ossowskitadeusz pyrazino23bindolizine10carbonitrile
AT sikorskiartur pyrazino23bindolizine10carbonitrile

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