Di-μ-iodido-bis­{[dicyclo­hexyl(phen­yl)phosphine-κP](pyridine-κN)silver(I)}

The title compound, [Ag(2)I(2)(C(5)H(5)N)(2)(C(18)H(27)P)(2)], contains centrosymmetric dinuclear species in which each Ag atom is surrounded by a phosphine ligand, a weakly coordinating pyridine ligand and two iodide anions in a distorted tetra­hedral coordination. The two iodide anions bridge the...

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Detalles Bibliográficos
Autores principales: Omondi, Bernard, Meijboom, Reinout
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969050/
https://www.ncbi.nlm.nih.gov/pubmed/21582395
http://dx.doi.org/10.1107/S160053680901099X
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author Omondi, Bernard
Meijboom, Reinout
author_facet Omondi, Bernard
Meijboom, Reinout
author_sort Omondi, Bernard
collection PubMed
description The title compound, [Ag(2)I(2)(C(5)H(5)N)(2)(C(18)H(27)P)(2)], contains centrosymmetric dinuclear species in which each Ag atom is surrounded by a phosphine ligand, a weakly coordinating pyridine ligand and two iodide anions in a distorted tetra­hedral coordination. The two iodide anions bridge the Ag atoms, which are separated by a distance of 3.1008 (6) Å. The Ag—P distance is 2.4436 (8) Å, Ag—N is 2.386 (3)Å and the Ag—I distances are 2.8186 (4) and 2.9449 (5) Å.
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spelling pubmed-29690502010-12-30 Di-μ-iodido-bis­{[dicyclo­hexyl(phen­yl)phosphine-κP](pyridine-κN)silver(I)} Omondi, Bernard Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ag(2)I(2)(C(5)H(5)N)(2)(C(18)H(27)P)(2)], contains centrosymmetric dinuclear species in which each Ag atom is surrounded by a phosphine ligand, a weakly coordinating pyridine ligand and two iodide anions in a distorted tetra­hedral coordination. The two iodide anions bridge the Ag atoms, which are separated by a distance of 3.1008 (6) Å. The Ag—P distance is 2.4436 (8) Å, Ag—N is 2.386 (3)Å and the Ag—I distances are 2.8186 (4) and 2.9449 (5) Å. International Union of Crystallography 2009-03-31 /pmc/articles/PMC2969050/ /pubmed/21582395 http://dx.doi.org/10.1107/S160053680901099X Text en © Omondi and Meijboom 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Omondi, Bernard
Meijboom, Reinout
Di-μ-iodido-bis­{[dicyclo­hexyl(phen­yl)phosphine-κP](pyridine-κN)silver(I)}
title Di-μ-iodido-bis­{[dicyclo­hexyl(phen­yl)phosphine-κP](pyridine-κN)silver(I)}
title_full Di-μ-iodido-bis­{[dicyclo­hexyl(phen­yl)phosphine-κP](pyridine-κN)silver(I)}
title_fullStr Di-μ-iodido-bis­{[dicyclo­hexyl(phen­yl)phosphine-κP](pyridine-κN)silver(I)}
title_full_unstemmed Di-μ-iodido-bis­{[dicyclo­hexyl(phen­yl)phosphine-κP](pyridine-κN)silver(I)}
title_short Di-μ-iodido-bis­{[dicyclo­hexyl(phen­yl)phosphine-κP](pyridine-κN)silver(I)}
title_sort di-μ-iodido-bis­{[dicyclo­hexyl(phen­yl)phosphine-κp](pyridine-κn)silver(i)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969050/
https://www.ncbi.nlm.nih.gov/pubmed/21582395
http://dx.doi.org/10.1107/S160053680901099X
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AT meijboomreinout dimiodidobisdicyclohexylphenylphosphinekppyridineknsilveri

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