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6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate
The title compound, C(22)H(20)N(2)O(4)·2CHCl(3), a new Schiff base compound, lies across a crystallographic inversion centre. An intramolecular O—H⋯N hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Intermolecular bifurcated C—H⋯O hydrogen bonds involving the two O atoms...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969051/ https://www.ncbi.nlm.nih.gov/pubmed/21582424 http://dx.doi.org/10.1107/S1600536809007302 |
Sumario: | The title compound, C(22)H(20)N(2)O(4)·2CHCl(3), a new Schiff base compound, lies across a crystallographic inversion centre. An intramolecular O—H⋯N hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Intermolecular bifurcated C—H⋯O hydrogen bonds involving the two O atoms of the Schiff base ligand and the H atom of the chloroform solvent of crystallization, generate an R (2) (1)(5) ring motif. The crystal structure is stabilized by intermolecular C—H⋯π and π–π interactions [centroid to centroid distance = 3.6158 (10) Å]. In the crystal structure, molecules are stacked down the c axis. |
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