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6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate
The title compound, C(22)H(20)N(2)O(4)·2CHCl(3), a new Schiff base compound, lies across a crystallographic inversion centre. An intramolecular O—H⋯N hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Intermolecular bifurcated C—H⋯O hydrogen bonds involving the two O atoms...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969051/ https://www.ncbi.nlm.nih.gov/pubmed/21582424 http://dx.doi.org/10.1107/S1600536809007302 |
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author | Al-Douh, Mohammed H. Osman, Hasnah Hamid, Shafida Abd. Kia, Reza Fun, Hoong-Kun |
author_facet | Al-Douh, Mohammed H. Osman, Hasnah Hamid, Shafida Abd. Kia, Reza Fun, Hoong-Kun |
author_sort | Al-Douh, Mohammed H. |
collection | PubMed |
description | The title compound, C(22)H(20)N(2)O(4)·2CHCl(3), a new Schiff base compound, lies across a crystallographic inversion centre. An intramolecular O—H⋯N hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Intermolecular bifurcated C—H⋯O hydrogen bonds involving the two O atoms of the Schiff base ligand and the H atom of the chloroform solvent of crystallization, generate an R (2) (1)(5) ring motif. The crystal structure is stabilized by intermolecular C—H⋯π and π–π interactions [centroid to centroid distance = 3.6158 (10) Å]. In the crystal structure, molecules are stacked down the c axis. |
format | Text |
id | pubmed-2969051 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29690512010-12-30 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate Al-Douh, Mohammed H. Osman, Hasnah Hamid, Shafida Abd. Kia, Reza Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(20)N(2)O(4)·2CHCl(3), a new Schiff base compound, lies across a crystallographic inversion centre. An intramolecular O—H⋯N hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Intermolecular bifurcated C—H⋯O hydrogen bonds involving the two O atoms of the Schiff base ligand and the H atom of the chloroform solvent of crystallization, generate an R (2) (1)(5) ring motif. The crystal structure is stabilized by intermolecular C—H⋯π and π–π interactions [centroid to centroid distance = 3.6158 (10) Å]. In the crystal structure, molecules are stacked down the c axis. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2969051/ /pubmed/21582424 http://dx.doi.org/10.1107/S1600536809007302 Text en © Al-Douh et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Al-Douh, Mohammed H. Osman, Hasnah Hamid, Shafida Abd. Kia, Reza Fun, Hoong-Kun 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate |
title | 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate |
title_full | 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate |
title_fullStr | 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate |
title_full_unstemmed | 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate |
title_short | 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate |
title_sort | 6,6′-dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969051/ https://www.ncbi.nlm.nih.gov/pubmed/21582424 http://dx.doi.org/10.1107/S1600536809007302 |
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