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6,6′-Dimeth­oxy-2,2′-[p-phenyl­ene­bis(nitrilo­methyl­idyne)]diphenol chloro­form disolvate

The title compound, C(22)H(20)N(2)O(4)·2CHCl(3), a new Schiff base compound, lies across a crystallographic inversion centre. An intra­molecular O—H⋯N hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Inter­molecular bifurcated C—H⋯O hydrogen bonds involving the two O atoms...

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Autores principales: Al-Douh, Mohammed H., Osman, Hasnah, Hamid, Shafida Abd., Kia, Reza, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969051/
https://www.ncbi.nlm.nih.gov/pubmed/21582424
http://dx.doi.org/10.1107/S1600536809007302
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author Al-Douh, Mohammed H.
Osman, Hasnah
Hamid, Shafida Abd.
Kia, Reza
Fun, Hoong-Kun
author_facet Al-Douh, Mohammed H.
Osman, Hasnah
Hamid, Shafida Abd.
Kia, Reza
Fun, Hoong-Kun
author_sort Al-Douh, Mohammed H.
collection PubMed
description The title compound, C(22)H(20)N(2)O(4)·2CHCl(3), a new Schiff base compound, lies across a crystallographic inversion centre. An intra­molecular O—H⋯N hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Inter­molecular bifurcated C—H⋯O hydrogen bonds involving the two O atoms of the Schiff base ligand and the H atom of the chloro­form solvent of crystallization, generate an R (2) (1)(5) ring motif. The crystal structure is stabilized by inter­molecular C—H⋯π and π–π inter­actions [centroid to centroid distance = 3.6158 (10) Å]. In the crystal structure, mol­ecules are stacked down the c axis.
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spelling pubmed-29690512010-12-30 6,6′-Dimeth­oxy-2,2′-[p-phenyl­ene­bis(nitrilo­methyl­idyne)]diphenol chloro­form disolvate Al-Douh, Mohammed H. Osman, Hasnah Hamid, Shafida Abd. Kia, Reza Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(20)N(2)O(4)·2CHCl(3), a new Schiff base compound, lies across a crystallographic inversion centre. An intra­molecular O—H⋯N hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Inter­molecular bifurcated C—H⋯O hydrogen bonds involving the two O atoms of the Schiff base ligand and the H atom of the chloro­form solvent of crystallization, generate an R (2) (1)(5) ring motif. The crystal structure is stabilized by inter­molecular C—H⋯π and π–π inter­actions [centroid to centroid distance = 3.6158 (10) Å]. In the crystal structure, mol­ecules are stacked down the c axis. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2969051/ /pubmed/21582424 http://dx.doi.org/10.1107/S1600536809007302 Text en © Al-Douh et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Al-Douh, Mohammed H.
Osman, Hasnah
Hamid, Shafida Abd.
Kia, Reza
Fun, Hoong-Kun
6,6′-Dimeth­oxy-2,2′-[p-phenyl­ene­bis(nitrilo­methyl­idyne)]diphenol chloro­form disolvate
title 6,6′-Dimeth­oxy-2,2′-[p-phenyl­ene­bis(nitrilo­methyl­idyne)]diphenol chloro­form disolvate
title_full 6,6′-Dimeth­oxy-2,2′-[p-phenyl­ene­bis(nitrilo­methyl­idyne)]diphenol chloro­form disolvate
title_fullStr 6,6′-Dimeth­oxy-2,2′-[p-phenyl­ene­bis(nitrilo­methyl­idyne)]diphenol chloro­form disolvate
title_full_unstemmed 6,6′-Dimeth­oxy-2,2′-[p-phenyl­ene­bis(nitrilo­methyl­idyne)]diphenol chloro­form disolvate
title_short 6,6′-Dimeth­oxy-2,2′-[p-phenyl­ene­bis(nitrilo­methyl­idyne)]diphenol chloro­form disolvate
title_sort 6,6′-dimeth­oxy-2,2′-[p-phenyl­ene­bis(nitrilo­methyl­idyne)]diphenol chloro­form disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969051/
https://www.ncbi.nlm.nih.gov/pubmed/21582424
http://dx.doi.org/10.1107/S1600536809007302
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