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Methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-[(Z)-methoxy­carbonyl­methoxy­imino]ethano­ate

In the mol­ecule of the title compound, C(9)H(11)N(3)O(5)S, the thia­zole ring is oriented at dihedral angles of 87.33 (3) and 87.18 (3)° with respect to the planar (r.m.s. deviations 0.0136 and 0.0139 Å) methyl ester groups. The dihedral angle between the methyl ester groups is 44.20 (3)°. In the c...

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Detalles Bibliográficos
Autores principales: Sharif, Shahzad, Tahir, M. Nawaz, Khan, Islam Ullah, Ahmad, Sarfraz, Salariya, Manan Ayub
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969052/
https://www.ncbi.nlm.nih.gov/pubmed/21582450
http://dx.doi.org/10.1107/S1600536809007661
Descripción
Sumario:In the mol­ecule of the title compound, C(9)H(11)N(3)O(5)S, the thia­zole ring is oriented at dihedral angles of 87.33 (3) and 87.18 (3)° with respect to the planar (r.m.s. deviations 0.0136 and 0.0139 Å) methyl ester groups. The dihedral angle between the methyl ester groups is 44.20 (3)°. In the crystal structure, inter­molecular N—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules along the a axis, through R (2) (2)(8) and R (2) (2)(22) ring motifs, forming infinite two-dimensional polymeric sheets. π–π Contacts between the thia­zole rings [centroid–centroid distance = 3.536 (2) Å] may further stabilize the structure.