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Methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(Z)-methoxycarbonylmethoxyimino]ethanoate
In the molecule of the title compound, C(9)H(11)N(3)O(5)S, the thiazole ring is oriented at dihedral angles of 87.33 (3) and 87.18 (3)° with respect to the planar (r.m.s. deviations 0.0136 and 0.0139 Å) methyl ester groups. The dihedral angle between the methyl ester groups is 44.20 (3)°. In the c...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969052/ https://www.ncbi.nlm.nih.gov/pubmed/21582450 http://dx.doi.org/10.1107/S1600536809007661 |
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author | Sharif, Shahzad Tahir, M. Nawaz Khan, Islam Ullah Ahmad, Sarfraz Salariya, Manan Ayub |
author_facet | Sharif, Shahzad Tahir, M. Nawaz Khan, Islam Ullah Ahmad, Sarfraz Salariya, Manan Ayub |
author_sort | Sharif, Shahzad |
collection | PubMed |
description | In the molecule of the title compound, C(9)H(11)N(3)O(5)S, the thiazole ring is oriented at dihedral angles of 87.33 (3) and 87.18 (3)° with respect to the planar (r.m.s. deviations 0.0136 and 0.0139 Å) methyl ester groups. The dihedral angle between the methyl ester groups is 44.20 (3)°. In the crystal structure, intermolecular N—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds link the molecules along the a axis, through R (2) (2)(8) and R (2) (2)(22) ring motifs, forming infinite two-dimensional polymeric sheets. π–π Contacts between the thiazole rings [centroid–centroid distance = 3.536 (2) Å] may further stabilize the structure. |
format | Text |
id | pubmed-2969052 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29690522010-12-30 Methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(Z)-methoxycarbonylmethoxyimino]ethanoate Sharif, Shahzad Tahir, M. Nawaz Khan, Islam Ullah Ahmad, Sarfraz Salariya, Manan Ayub Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(9)H(11)N(3)O(5)S, the thiazole ring is oriented at dihedral angles of 87.33 (3) and 87.18 (3)° with respect to the planar (r.m.s. deviations 0.0136 and 0.0139 Å) methyl ester groups. The dihedral angle between the methyl ester groups is 44.20 (3)°. In the crystal structure, intermolecular N—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds link the molecules along the a axis, through R (2) (2)(8) and R (2) (2)(22) ring motifs, forming infinite two-dimensional polymeric sheets. π–π Contacts between the thiazole rings [centroid–centroid distance = 3.536 (2) Å] may further stabilize the structure. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2969052/ /pubmed/21582450 http://dx.doi.org/10.1107/S1600536809007661 Text en © Sharif et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sharif, Shahzad Tahir, M. Nawaz Khan, Islam Ullah Ahmad, Sarfraz Salariya, Manan Ayub Methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(Z)-methoxycarbonylmethoxyimino]ethanoate |
title | Methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(Z)-methoxycarbonylmethoxyimino]ethanoate |
title_full | Methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(Z)-methoxycarbonylmethoxyimino]ethanoate |
title_fullStr | Methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(Z)-methoxycarbonylmethoxyimino]ethanoate |
title_full_unstemmed | Methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(Z)-methoxycarbonylmethoxyimino]ethanoate |
title_short | Methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(Z)-methoxycarbonylmethoxyimino]ethanoate |
title_sort | methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(z)-methoxycarbonylmethoxyimino]ethanoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969052/ https://www.ncbi.nlm.nih.gov/pubmed/21582450 http://dx.doi.org/10.1107/S1600536809007661 |
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