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Methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-[(Z)-methoxy­carbonyl­methoxy­imino]ethano­ate

In the mol­ecule of the title compound, C(9)H(11)N(3)O(5)S, the thia­zole ring is oriented at dihedral angles of 87.33 (3) and 87.18 (3)° with respect to the planar (r.m.s. deviations 0.0136 and 0.0139 Å) methyl ester groups. The dihedral angle between the methyl ester groups is 44.20 (3)°. In the c...

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Autores principales: Sharif, Shahzad, Tahir, M. Nawaz, Khan, Islam Ullah, Ahmad, Sarfraz, Salariya, Manan Ayub
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969052/
https://www.ncbi.nlm.nih.gov/pubmed/21582450
http://dx.doi.org/10.1107/S1600536809007661
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author Sharif, Shahzad
Tahir, M. Nawaz
Khan, Islam Ullah
Ahmad, Sarfraz
Salariya, Manan Ayub
author_facet Sharif, Shahzad
Tahir, M. Nawaz
Khan, Islam Ullah
Ahmad, Sarfraz
Salariya, Manan Ayub
author_sort Sharif, Shahzad
collection PubMed
description In the mol­ecule of the title compound, C(9)H(11)N(3)O(5)S, the thia­zole ring is oriented at dihedral angles of 87.33 (3) and 87.18 (3)° with respect to the planar (r.m.s. deviations 0.0136 and 0.0139 Å) methyl ester groups. The dihedral angle between the methyl ester groups is 44.20 (3)°. In the crystal structure, inter­molecular N—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules along the a axis, through R (2) (2)(8) and R (2) (2)(22) ring motifs, forming infinite two-dimensional polymeric sheets. π–π Contacts between the thia­zole rings [centroid–centroid distance = 3.536 (2) Å] may further stabilize the structure.
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spelling pubmed-29690522010-12-30 Methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-[(Z)-methoxy­carbonyl­methoxy­imino]ethano­ate Sharif, Shahzad Tahir, M. Nawaz Khan, Islam Ullah Ahmad, Sarfraz Salariya, Manan Ayub Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(9)H(11)N(3)O(5)S, the thia­zole ring is oriented at dihedral angles of 87.33 (3) and 87.18 (3)° with respect to the planar (r.m.s. deviations 0.0136 and 0.0139 Å) methyl ester groups. The dihedral angle between the methyl ester groups is 44.20 (3)°. In the crystal structure, inter­molecular N—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules along the a axis, through R (2) (2)(8) and R (2) (2)(22) ring motifs, forming infinite two-dimensional polymeric sheets. π–π Contacts between the thia­zole rings [centroid–centroid distance = 3.536 (2) Å] may further stabilize the structure. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2969052/ /pubmed/21582450 http://dx.doi.org/10.1107/S1600536809007661 Text en © Sharif et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sharif, Shahzad
Tahir, M. Nawaz
Khan, Islam Ullah
Ahmad, Sarfraz
Salariya, Manan Ayub
Methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-[(Z)-methoxy­carbonyl­methoxy­imino]ethano­ate
title Methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-[(Z)-methoxy­carbonyl­methoxy­imino]ethano­ate
title_full Methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-[(Z)-methoxy­carbonyl­methoxy­imino]ethano­ate
title_fullStr Methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-[(Z)-methoxy­carbonyl­methoxy­imino]ethano­ate
title_full_unstemmed Methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-[(Z)-methoxy­carbonyl­methoxy­imino]ethano­ate
title_short Methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-[(Z)-methoxy­carbonyl­methoxy­imino]ethano­ate
title_sort methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-[(z)-methoxy­carbonyl­methoxy­imino]ethano­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969052/
https://www.ncbi.nlm.nih.gov/pubmed/21582450
http://dx.doi.org/10.1107/S1600536809007661
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