Bis[μ-5-(5-carboxyl­ato-3-pyrid­yl)tetra­zolato-κ(3) N (1),N (5):N (2)]bis­[triaqua­zinc(II)]

In the title complex, [Zn(2)(C(7)H(3)N(5)O(2))(2)(H(2)O)(6)], the 5-(5-carboxyl­ato-3-pyrid­yl)tetra­zolate ligand chelates the Zn(II) center through one pyridyl N and one tetra­zolate N atom, and uses another N atom to bridge to the second Zn atom, forming a centrosymmetric dinuclear unit. Three co...

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Detalles Bibliográficos
Autores principales: Yin, Haoyong, Wang, Ling, Nie, Qiulin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969057/
https://www.ncbi.nlm.nih.gov/pubmed/21582366
http://dx.doi.org/10.1107/S1600536809009660
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author Yin, Haoyong
Wang, Ling
Nie, Qiulin
author_facet Yin, Haoyong
Wang, Ling
Nie, Qiulin
author_sort Yin, Haoyong
collection PubMed
description In the title complex, [Zn(2)(C(7)H(3)N(5)O(2))(2)(H(2)O)(6)], the 5-(5-carboxyl­ato-3-pyrid­yl)tetra­zolate ligand chelates the Zn(II) center through one pyridyl N and one tetra­zolate N atom, and uses another N atom to bridge to the second Zn atom, forming a centrosymmetric dinuclear unit. Three coordinated water mol­ecules complete the distorted octa­hedral geometry of the Zn(II) atom. O—H⋯O and O—H⋯N hydrogen bonds involving the coordinated water mol­ecules, tetra­zolate N atoms and the carboxyl­ate group result in a three-dimensional structure.
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spelling pubmed-29690572010-12-30 Bis[μ-5-(5-carboxyl­ato-3-pyrid­yl)tetra­zolato-κ(3) N (1),N (5):N (2)]bis­[triaqua­zinc(II)] Yin, Haoyong Wang, Ling Nie, Qiulin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(2)(C(7)H(3)N(5)O(2))(2)(H(2)O)(6)], the 5-(5-carboxyl­ato-3-pyrid­yl)tetra­zolate ligand chelates the Zn(II) center through one pyridyl N and one tetra­zolate N atom, and uses another N atom to bridge to the second Zn atom, forming a centrosymmetric dinuclear unit. Three coordinated water mol­ecules complete the distorted octa­hedral geometry of the Zn(II) atom. O—H⋯O and O—H⋯N hydrogen bonds involving the coordinated water mol­ecules, tetra­zolate N atoms and the carboxyl­ate group result in a three-dimensional structure. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2969057/ /pubmed/21582366 http://dx.doi.org/10.1107/S1600536809009660 Text en © Yin et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yin, Haoyong
Wang, Ling
Nie, Qiulin
Bis[μ-5-(5-carboxyl­ato-3-pyrid­yl)tetra­zolato-κ(3) N (1),N (5):N (2)]bis­[triaqua­zinc(II)]
title Bis[μ-5-(5-carboxyl­ato-3-pyrid­yl)tetra­zolato-κ(3) N (1),N (5):N (2)]bis­[triaqua­zinc(II)]
title_full Bis[μ-5-(5-carboxyl­ato-3-pyrid­yl)tetra­zolato-κ(3) N (1),N (5):N (2)]bis­[triaqua­zinc(II)]
title_fullStr Bis[μ-5-(5-carboxyl­ato-3-pyrid­yl)tetra­zolato-κ(3) N (1),N (5):N (2)]bis­[triaqua­zinc(II)]
title_full_unstemmed Bis[μ-5-(5-carboxyl­ato-3-pyrid­yl)tetra­zolato-κ(3) N (1),N (5):N (2)]bis­[triaqua­zinc(II)]
title_short Bis[μ-5-(5-carboxyl­ato-3-pyrid­yl)tetra­zolato-κ(3) N (1),N (5):N (2)]bis­[triaqua­zinc(II)]
title_sort bis[μ-5-(5-carboxyl­ato-3-pyrid­yl)tetra­zolato-κ(3) n (1),n (5):n (2)]bis­[triaqua­zinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969057/
https://www.ncbi.nlm.nih.gov/pubmed/21582366
http://dx.doi.org/10.1107/S1600536809009660
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AT wangling bism55carboxylato3pyridyltetrazolatok3n1n5n2bistriaquazincii
AT nieqiulin bism55carboxylato3pyridyltetrazolatok3n1n5n2bistriaquazincii

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