Bis(η(5)-penta­methyl­cyclo­penta­dien­yl)cobalt(II)

The crystal structure of the title compound, deca­methyl­cobaltocene, [Co(C(10)H(15))(2)], has been determined. High-quality single crystals were grown from a cold saturated hexa­methyl­disiloxane solution. The structure is related to the manganese and iron analogs. The molecule has D (5d) symmetry,...

Descripción completa

Detalles Bibliográficos
Autores principales: Clark, Meghan M., Brennessel, William W., Holland, Patrick L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969061/
https://www.ncbi.nlm.nih.gov/pubmed/21582340
http://dx.doi.org/10.1107/S1600536809007971
_version_ 1782190053614682112
author Clark, Meghan M.
Brennessel, William W.
Holland, Patrick L.
author_facet Clark, Meghan M.
Brennessel, William W.
Holland, Patrick L.
author_sort Clark, Meghan M.
collection PubMed
description The crystal structure of the title compound, deca­methyl­cobaltocene, [Co(C(10)H(15))(2)], has been determined. High-quality single crystals were grown from a cold saturated hexa­methyl­disiloxane solution. The structure is related to the manganese and iron analogs. The molecule has D (5d) symmetry, with the Co atom in a crystallographic 2/m position. The cobalt–centroid(C(5)) distance is 1.71Å and the centroid(C(5))–Co–centroid(C(5)) angle is 180°, by symmetry.
format Text
id pubmed-2969061
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29690612010-12-30 Bis(η(5)-penta­methyl­cyclo­penta­dien­yl)cobalt(II) Clark, Meghan M. Brennessel, William W. Holland, Patrick L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, deca­methyl­cobaltocene, [Co(C(10)H(15))(2)], has been determined. High-quality single crystals were grown from a cold saturated hexa­methyl­disiloxane solution. The structure is related to the manganese and iron analogs. The molecule has D (5d) symmetry, with the Co atom in a crystallographic 2/m position. The cobalt–centroid(C(5)) distance is 1.71Å and the centroid(C(5))–Co–centroid(C(5)) angle is 180°, by symmetry. International Union of Crystallography 2009-03-11 /pmc/articles/PMC2969061/ /pubmed/21582340 http://dx.doi.org/10.1107/S1600536809007971 Text en © Clark et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Clark, Meghan M.
Brennessel, William W.
Holland, Patrick L.
Bis(η(5)-penta­methyl­cyclo­penta­dien­yl)cobalt(II)
title Bis(η(5)-penta­methyl­cyclo­penta­dien­yl)cobalt(II)
title_full Bis(η(5)-penta­methyl­cyclo­penta­dien­yl)cobalt(II)
title_fullStr Bis(η(5)-penta­methyl­cyclo­penta­dien­yl)cobalt(II)
title_full_unstemmed Bis(η(5)-penta­methyl­cyclo­penta­dien­yl)cobalt(II)
title_short Bis(η(5)-penta­methyl­cyclo­penta­dien­yl)cobalt(II)
title_sort bis(η(5)-penta­methyl­cyclo­penta­dien­yl)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969061/
https://www.ncbi.nlm.nih.gov/pubmed/21582340
http://dx.doi.org/10.1107/S1600536809007971
work_keys_str_mv AT clarkmeghanm bisē5pentamethylcyclopentadienylcobaltii
AT brennesselwilliamw bisē5pentamethylcyclopentadienylcobaltii
AT hollandpatrickl bisē5pentamethylcyclopentadienylcobaltii

Ejemplares similares