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Poly[hemi(ethyl­enediammonium) [di-μ-oxalato-indium(III)] dihydrate]

In title compound, {(C(2)H(10)N(2))(0.5)[In(C(2)O(4))(2)]·2H(2)O}(n), the unique In(III) ion is coordinated by eight O atoms from four oxalate ligands in a distorted square-anti­prismatic environment. The doubly bis-chelating oxalate ligands act as bridging ligands connecting symmetry-related In(III...

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Detalles Bibliográficos
Autores principales: Sun, Qiaozhen, Liu, Yang, Li, Hongwu, Luo, Zhi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969062/
https://www.ncbi.nlm.nih.gov/pubmed/21582342
http://dx.doi.org/10.1107/S1600536809008381
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author Sun, Qiaozhen
Liu, Yang
Li, Hongwu
Luo, Zhi
author_facet Sun, Qiaozhen
Liu, Yang
Li, Hongwu
Luo, Zhi
author_sort Sun, Qiaozhen
collection PubMed
description In title compound, {(C(2)H(10)N(2))(0.5)[In(C(2)O(4))(2)]·2H(2)O}(n), the unique In(III) ion is coordinated by eight O atoms from four oxalate ligands in a distorted square-anti­prismatic environment. The doubly bis-chelating oxalate ligands act as bridging ligands connecting symmetry-related In(III) ions and forming a three-dimensional open framework structure. Ethyl­enediammonium cations and water mol­ecules occupy the voids within the structure. The unique ethyl­enediammonium cation and one water mol­ecule both lie on a twofold rotation axis. One of the other two water mol­ecules residing on general crystallographic sites was refined as disordered with half occupancy. In the crystal structure, cations and water mol­ecules are linked to the anionic framework via inter­molecular O—H⋯O and N—H⋯O hydrogen bonds.
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spelling pubmed-29690622010-12-30 Poly[hemi(ethyl­enediammonium) [di-μ-oxalato-indium(III)] dihydrate] Sun, Qiaozhen Liu, Yang Li, Hongwu Luo, Zhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In title compound, {(C(2)H(10)N(2))(0.5)[In(C(2)O(4))(2)]·2H(2)O}(n), the unique In(III) ion is coordinated by eight O atoms from four oxalate ligands in a distorted square-anti­prismatic environment. The doubly bis-chelating oxalate ligands act as bridging ligands connecting symmetry-related In(III) ions and forming a three-dimensional open framework structure. Ethyl­enediammonium cations and water mol­ecules occupy the voids within the structure. The unique ethyl­enediammonium cation and one water mol­ecule both lie on a twofold rotation axis. One of the other two water mol­ecules residing on general crystallographic sites was refined as disordered with half occupancy. In the crystal structure, cations and water mol­ecules are linked to the anionic framework via inter­molecular O—H⋯O and N—H⋯O hydrogen bonds. International Union of Crystallography 2009-03-14 /pmc/articles/PMC2969062/ /pubmed/21582342 http://dx.doi.org/10.1107/S1600536809008381 Text en © Sun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Qiaozhen
Liu, Yang
Li, Hongwu
Luo, Zhi
Poly[hemi(ethyl­enediammonium) [di-μ-oxalato-indium(III)] dihydrate]
title Poly[hemi(ethyl­enediammonium) [di-μ-oxalato-indium(III)] dihydrate]
title_full Poly[hemi(ethyl­enediammonium) [di-μ-oxalato-indium(III)] dihydrate]
title_fullStr Poly[hemi(ethyl­enediammonium) [di-μ-oxalato-indium(III)] dihydrate]
title_full_unstemmed Poly[hemi(ethyl­enediammonium) [di-μ-oxalato-indium(III)] dihydrate]
title_short Poly[hemi(ethyl­enediammonium) [di-μ-oxalato-indium(III)] dihydrate]
title_sort poly[hemi(ethyl­enediammonium) [di-μ-oxalato-indium(iii)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969062/
https://www.ncbi.nlm.nih.gov/pubmed/21582342
http://dx.doi.org/10.1107/S1600536809008381
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AT luozhi polyhemiethylenediammoniumdimoxalatoindiumiiidihydrate