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Poly[hemi(ethylenediammonium) [di-μ-oxalato-indium(III)] dihydrate]
In title compound, {(C(2)H(10)N(2))(0.5)[In(C(2)O(4))(2)]·2H(2)O}(n), the unique In(III) ion is coordinated by eight O atoms from four oxalate ligands in a distorted square-antiprismatic environment. The doubly bis-chelating oxalate ligands act as bridging ligands connecting symmetry-related In(III...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969062/ https://www.ncbi.nlm.nih.gov/pubmed/21582342 http://dx.doi.org/10.1107/S1600536809008381 |
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author | Sun, Qiaozhen Liu, Yang Li, Hongwu Luo, Zhi |
author_facet | Sun, Qiaozhen Liu, Yang Li, Hongwu Luo, Zhi |
author_sort | Sun, Qiaozhen |
collection | PubMed |
description | In title compound, {(C(2)H(10)N(2))(0.5)[In(C(2)O(4))(2)]·2H(2)O}(n), the unique In(III) ion is coordinated by eight O atoms from four oxalate ligands in a distorted square-antiprismatic environment. The doubly bis-chelating oxalate ligands act as bridging ligands connecting symmetry-related In(III) ions and forming a three-dimensional open framework structure. Ethylenediammonium cations and water molecules occupy the voids within the structure. The unique ethylenediammonium cation and one water molecule both lie on a twofold rotation axis. One of the other two water molecules residing on general crystallographic sites was refined as disordered with half occupancy. In the crystal structure, cations and water molecules are linked to the anionic framework via intermolecular O—H⋯O and N—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2969062 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29690622010-12-30 Poly[hemi(ethylenediammonium) [di-μ-oxalato-indium(III)] dihydrate] Sun, Qiaozhen Liu, Yang Li, Hongwu Luo, Zhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In title compound, {(C(2)H(10)N(2))(0.5)[In(C(2)O(4))(2)]·2H(2)O}(n), the unique In(III) ion is coordinated by eight O atoms from four oxalate ligands in a distorted square-antiprismatic environment. The doubly bis-chelating oxalate ligands act as bridging ligands connecting symmetry-related In(III) ions and forming a three-dimensional open framework structure. Ethylenediammonium cations and water molecules occupy the voids within the structure. The unique ethylenediammonium cation and one water molecule both lie on a twofold rotation axis. One of the other two water molecules residing on general crystallographic sites was refined as disordered with half occupancy. In the crystal structure, cations and water molecules are linked to the anionic framework via intermolecular O—H⋯O and N—H⋯O hydrogen bonds. International Union of Crystallography 2009-03-14 /pmc/articles/PMC2969062/ /pubmed/21582342 http://dx.doi.org/10.1107/S1600536809008381 Text en © Sun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sun, Qiaozhen Liu, Yang Li, Hongwu Luo, Zhi Poly[hemi(ethylenediammonium) [di-μ-oxalato-indium(III)] dihydrate] |
title | Poly[hemi(ethylenediammonium) [di-μ-oxalato-indium(III)] dihydrate] |
title_full | Poly[hemi(ethylenediammonium) [di-μ-oxalato-indium(III)] dihydrate] |
title_fullStr | Poly[hemi(ethylenediammonium) [di-μ-oxalato-indium(III)] dihydrate] |
title_full_unstemmed | Poly[hemi(ethylenediammonium) [di-μ-oxalato-indium(III)] dihydrate] |
title_short | Poly[hemi(ethylenediammonium) [di-μ-oxalato-indium(III)] dihydrate] |
title_sort | poly[hemi(ethylenediammonium) [di-μ-oxalato-indium(iii)] dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969062/ https://www.ncbi.nlm.nih.gov/pubmed/21582342 http://dx.doi.org/10.1107/S1600536809008381 |
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