Diaqua­[N,N′-bis­(3-carboxy­prop-2-enoyl)pyridine-2,6-dicarbo­hydrazidato(2–)]cadmium(II) N,N-dimethyl­formamide disolvate

In the title complex, [Cd(C(15)H(11)N(5)O(8))(H(2)O)(2)]·2C(3)H(7)NO, the Cd(II) ion is located on a twofold rotation axis and is seven-coordinated in a distorted penta­gonal-bipyramidal manner. The asymmetric unit comprises one metal ion, one doubly deprotonated N,N′-bis­(3-carboxy­prop-2-eno­yl)py...

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Detalles Bibliográficos
Autores principales: Cao, Quanfu, Li, Dacheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969067/
https://www.ncbi.nlm.nih.gov/pubmed/21582396
http://dx.doi.org/10.1107/S1600536809011003
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author Cao, Quanfu
Li, Dacheng
author_facet Cao, Quanfu
Li, Dacheng
author_sort Cao, Quanfu
collection PubMed
description In the title complex, [Cd(C(15)H(11)N(5)O(8))(H(2)O)(2)]·2C(3)H(7)NO, the Cd(II) ion is located on a twofold rotation axis and is seven-coordinated in a distorted penta­gonal-bipyramidal manner. The asymmetric unit comprises one metal ion, one doubly deprotonated N,N′-bis­(3-carboxy­prop-2-eno­yl)pyridine-2,6-dicarbohydrazide ligand, two coordinating water mol­ecules and two dimethyl­formamide solvent mol­ecules. In the crystal, a two-dimensional network is formed through N—H⋯O and O—H⋯O hydrogen bonds.
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spelling pubmed-29690672010-12-30 Diaqua­[N,N′-bis­(3-carboxy­prop-2-enoyl)pyridine-2,6-dicarbo­hydrazidato(2–)]cadmium(II) N,N-dimethyl­formamide disolvate Cao, Quanfu Li, Dacheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(15)H(11)N(5)O(8))(H(2)O)(2)]·2C(3)H(7)NO, the Cd(II) ion is located on a twofold rotation axis and is seven-coordinated in a distorted penta­gonal-bipyramidal manner. The asymmetric unit comprises one metal ion, one doubly deprotonated N,N′-bis­(3-carboxy­prop-2-eno­yl)pyridine-2,6-dicarbohydrazide ligand, two coordinating water mol­ecules and two dimethyl­formamide solvent mol­ecules. In the crystal, a two-dimensional network is formed through N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2009-03-31 /pmc/articles/PMC2969067/ /pubmed/21582396 http://dx.doi.org/10.1107/S1600536809011003 Text en © Cao and Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cao, Quanfu
Li, Dacheng
Diaqua­[N,N′-bis­(3-carboxy­prop-2-enoyl)pyridine-2,6-dicarbo­hydrazidato(2–)]cadmium(II) N,N-dimethyl­formamide disolvate
title Diaqua­[N,N′-bis­(3-carboxy­prop-2-enoyl)pyridine-2,6-dicarbo­hydrazidato(2–)]cadmium(II) N,N-dimethyl­formamide disolvate
title_full Diaqua­[N,N′-bis­(3-carboxy­prop-2-enoyl)pyridine-2,6-dicarbo­hydrazidato(2–)]cadmium(II) N,N-dimethyl­formamide disolvate
title_fullStr Diaqua­[N,N′-bis­(3-carboxy­prop-2-enoyl)pyridine-2,6-dicarbo­hydrazidato(2–)]cadmium(II) N,N-dimethyl­formamide disolvate
title_full_unstemmed Diaqua­[N,N′-bis­(3-carboxy­prop-2-enoyl)pyridine-2,6-dicarbo­hydrazidato(2–)]cadmium(II) N,N-dimethyl­formamide disolvate
title_short Diaqua­[N,N′-bis­(3-carboxy­prop-2-enoyl)pyridine-2,6-dicarbo­hydrazidato(2–)]cadmium(II) N,N-dimethyl­formamide disolvate
title_sort diaqua­[n,n′-bis­(3-carboxy­prop-2-enoyl)pyridine-2,6-dicarbo­hydrazidato(2–)]cadmium(ii) n,n-dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969067/
https://www.ncbi.nlm.nih.gov/pubmed/21582396
http://dx.doi.org/10.1107/S1600536809011003
work_keys_str_mv AT caoquanfu diaquannbis3carboxyprop2enoylpyridine26dicarbohydrazidato2cadmiumiinndimethylformamidedisolvate
AT lidacheng diaquannbis3carboxyprop2enoylpyridine26dicarbohydrazidato2cadmiumiinndimethylformamidedisolvate

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