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4,4′-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile
The molecule of the title Schiff base compound, C(18)H(14)N(4), lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine (C=N) bonds. The imino groups are coplanar with the aromatic rings with a maximum deviation of 0.1574 (12) Å for the N atom. W...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969074/ https://www.ncbi.nlm.nih.gov/pubmed/21582425 http://dx.doi.org/10.1107/S1600536809007284 |
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author | Kia, Reza Fun, Hoong-Kun Kargar, Hadi |
author_facet | Kia, Reza Fun, Hoong-Kun Kargar, Hadi |
author_sort | Kia, Reza |
collection | PubMed |
description | The molecule of the title Schiff base compound, C(18)H(14)N(4), lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine (C=N) bonds. The imino groups are coplanar with the aromatic rings with a maximum deviation of 0.1574 (12) Å for the N atom. Within the molecule, the planar units are parallel, but extend in opposite directions from the dimethylene bridge. In the crystal structure, pairs of intermolecular C—H⋯N hydrogen bonds link neighbouring molecules into centrosymmetric dimers with R (2) (2)(10) ring motifs. An interesting feature of the crystal structure is the short intermolecular C⋯C interaction with a distance of 3.3821 (13) Å, which is shorter than the sum of the van der Waals radius of a carbon atom. |
format | Text |
id | pubmed-2969074 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29690742010-12-30 4,4′-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile Kia, Reza Fun, Hoong-Kun Kargar, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title Schiff base compound, C(18)H(14)N(4), lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine (C=N) bonds. The imino groups are coplanar with the aromatic rings with a maximum deviation of 0.1574 (12) Å for the N atom. Within the molecule, the planar units are parallel, but extend in opposite directions from the dimethylene bridge. In the crystal structure, pairs of intermolecular C—H⋯N hydrogen bonds link neighbouring molecules into centrosymmetric dimers with R (2) (2)(10) ring motifs. An interesting feature of the crystal structure is the short intermolecular C⋯C interaction with a distance of 3.3821 (13) Å, which is shorter than the sum of the van der Waals radius of a carbon atom. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2969074/ /pubmed/21582425 http://dx.doi.org/10.1107/S1600536809007284 Text en © Kia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kia, Reza Fun, Hoong-Kun Kargar, Hadi 4,4′-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile |
title | 4,4′-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile |
title_full | 4,4′-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile |
title_fullStr | 4,4′-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile |
title_full_unstemmed | 4,4′-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile |
title_short | 4,4′-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile |
title_sort | 4,4′-[ethylenebis(nitrilomethylidyne)]dibenzonitrile |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969074/ https://www.ncbi.nlm.nih.gov/pubmed/21582425 http://dx.doi.org/10.1107/S1600536809007284 |
work_keys_str_mv | AT kiareza 44ethylenebisnitrilomethylidynedibenzonitrile AT funhoongkun 44ethylenebisnitrilomethylidynedibenzonitrile AT kargarhadi 44ethylenebisnitrilomethylidynedibenzonitrile |