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4,4′-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile

The mol­ecule of the title Schiff base compound, C(18)H(14)N(4), lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine (C=N) bonds. The imino groups are coplanar with the aromatic rings with a maximum deviation of 0.1574 (12) Å for the N atom. W...

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Detalles Bibliográficos
Autores principales: Kia, Reza, Fun, Hoong-Kun, Kargar, Hadi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969074/
https://www.ncbi.nlm.nih.gov/pubmed/21582425
http://dx.doi.org/10.1107/S1600536809007284
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author Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
author_facet Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
author_sort Kia, Reza
collection PubMed
description The mol­ecule of the title Schiff base compound, C(18)H(14)N(4), lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine (C=N) bonds. The imino groups are coplanar with the aromatic rings with a maximum deviation of 0.1574 (12) Å for the N atom. Within the mol­ecule, the planar units are parallel, but extend in opposite directions from the dimethyl­ene bridge. In the crystal structure, pairs of inter­molecular C—H⋯N hydrogen bonds link neighbouring mol­ecules into centrosymmetric dimers with R (2) (2)(10) ring motifs. An inter­esting feature of the crystal structure is the short inter­molecular C⋯C inter­action with a distance of 3.3821 (13) Å, which is shorter than the sum of the van der Waals radius of a carbon atom.
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spelling pubmed-29690742010-12-30 4,4′-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile Kia, Reza Fun, Hoong-Kun Kargar, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title Schiff base compound, C(18)H(14)N(4), lies across a crystallographic inversion centre and adopts an E configuration with respect to the azomethine (C=N) bonds. The imino groups are coplanar with the aromatic rings with a maximum deviation of 0.1574 (12) Å for the N atom. Within the mol­ecule, the planar units are parallel, but extend in opposite directions from the dimethyl­ene bridge. In the crystal structure, pairs of inter­molecular C—H⋯N hydrogen bonds link neighbouring mol­ecules into centrosymmetric dimers with R (2) (2)(10) ring motifs. An inter­esting feature of the crystal structure is the short inter­molecular C⋯C inter­action with a distance of 3.3821 (13) Å, which is shorter than the sum of the van der Waals radius of a carbon atom. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2969074/ /pubmed/21582425 http://dx.doi.org/10.1107/S1600536809007284 Text en © Kia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
4,4′-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile
title 4,4′-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile
title_full 4,4′-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile
title_fullStr 4,4′-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile
title_full_unstemmed 4,4′-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile
title_short 4,4′-[Ethylenebis(nitrilomethylidyne)]dibenzonitrile
title_sort 4,4′-[ethylenebis(nitrilomethylidyne)]dibenzonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969074/
https://www.ncbi.nlm.nih.gov/pubmed/21582425
http://dx.doi.org/10.1107/S1600536809007284
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