Bis(ferrocenecarbaldehyde thio­semi­carbazonato-κ(2) N (1),S)zinc

In the title compound, [Fe(2)Zn(C(5)H(5))(2)(C(7)H(7)N(3)S)(2)], the Cp rings of each ferrocene residue have a nearly eclipsed conformation. The two thio­semicarbazone ligands each coordinate the Zn atom in a bidentate mode via the N and S atoms, thereby defining a distorted tetra­hedral environment...

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Detalles Bibliográficos
Autores principales: Vikneswaran, M. R., Teoh, Siang Guan, Razak, Ibrahim Abdul, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969079/
https://www.ncbi.nlm.nih.gov/pubmed/21582327
http://dx.doi.org/10.1107/S1600536809007363
Descripción
Sumario:In the title compound, [Fe(2)Zn(C(5)H(5))(2)(C(7)H(7)N(3)S)(2)], the Cp rings of each ferrocene residue have a nearly eclipsed conformation. The two thio­semicarbazone ligands each coordinate the Zn atom in a bidentate mode via the N and S atoms, thereby defining a distorted tetra­hedral environment. N—H⋯S, N—H⋯N, C—H⋯S and C—H⋯N intra- and intermol­ecular inter­actions connect the mol­ecules into a two-dimensional array parallel to (010).

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