N-(2-Ferrocenylethyl­idene)-4-(trifluoro­meth­yl)aniline

The title compound, [Fe(C(5)H(5))(C(13)H(9)F(3)N)], was prepared by a condensation reaction from ferrocenylcarbaldehyde and 4-(trifluoro­meth­yl)aniline. The cyclo­penta­dienyl (Cp) rings are coplanar [dihedral angle = 1.4 (3)°] and the imine function is situated in the same plane. The aromatic subs...

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Detalles Bibliográficos
Autor principal: Imhof, Wolfgang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969081/
https://www.ncbi.nlm.nih.gov/pubmed/21582394
http://dx.doi.org/10.1107/S1600536809011039
Descripción
Sumario:The title compound, [Fe(C(5)H(5))(C(13)H(9)F(3)N)], was prepared by a condensation reaction from ferrocenylcarbaldehyde and 4-(trifluoro­meth­yl)aniline. The cyclo­penta­dienyl (Cp) rings are coplanar [dihedral angle = 1.4 (3)°] and the imine function is situated in the same plane. The aromatic substituent is bent out of the plane of the Cp ring to which the imine group is attached by 44.5 (4)°. The F atoms of the trifluoro­methyl substituent are disordered [occupancies 0.52 (2)/0.48 (2)].

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