N-(2-Ferrocenylethyl­idene)-4-(trifluoro­meth­yl)aniline

The title compound, [Fe(C(5)H(5))(C(13)H(9)F(3)N)], was prepared by a condensation reaction from ferrocenylcarbaldehyde and 4-(trifluoro­meth­yl)aniline. The cyclo­penta­dienyl (Cp) rings are coplanar [dihedral angle = 1.4 (3)°] and the imine function is situated in the same plane. The aromatic subs...

Descripción completa

Detalles Bibliográficos
Autor principal: Imhof, Wolfgang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969081/
https://www.ncbi.nlm.nih.gov/pubmed/21582394
http://dx.doi.org/10.1107/S1600536809011039
_version_ 1782190059697471488
author Imhof, Wolfgang
author_facet Imhof, Wolfgang
author_sort Imhof, Wolfgang
collection PubMed
description The title compound, [Fe(C(5)H(5))(C(13)H(9)F(3)N)], was prepared by a condensation reaction from ferrocenylcarbaldehyde and 4-(trifluoro­meth­yl)aniline. The cyclo­penta­dienyl (Cp) rings are coplanar [dihedral angle = 1.4 (3)°] and the imine function is situated in the same plane. The aromatic substituent is bent out of the plane of the Cp ring to which the imine group is attached by 44.5 (4)°. The F atoms of the trifluoro­methyl substituent are disordered [occupancies 0.52 (2)/0.48 (2)].
format Text
id pubmed-2969081
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29690812010-12-30 N-(2-Ferrocenylethyl­idene)-4-(trifluoro­meth­yl)aniline Imhof, Wolfgang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(5)H(5))(C(13)H(9)F(3)N)], was prepared by a condensation reaction from ferrocenylcarbaldehyde and 4-(trifluoro­meth­yl)aniline. The cyclo­penta­dienyl (Cp) rings are coplanar [dihedral angle = 1.4 (3)°] and the imine function is situated in the same plane. The aromatic substituent is bent out of the plane of the Cp ring to which the imine group is attached by 44.5 (4)°. The F atoms of the trifluoro­methyl substituent are disordered [occupancies 0.52 (2)/0.48 (2)]. International Union of Crystallography 2009-03-28 /pmc/articles/PMC2969081/ /pubmed/21582394 http://dx.doi.org/10.1107/S1600536809011039 Text en © Wolfgang Imhof 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Imhof, Wolfgang
N-(2-Ferrocenylethyl­idene)-4-(trifluoro­meth­yl)aniline
title N-(2-Ferrocenylethyl­idene)-4-(trifluoro­meth­yl)aniline
title_full N-(2-Ferrocenylethyl­idene)-4-(trifluoro­meth­yl)aniline
title_fullStr N-(2-Ferrocenylethyl­idene)-4-(trifluoro­meth­yl)aniline
title_full_unstemmed N-(2-Ferrocenylethyl­idene)-4-(trifluoro­meth­yl)aniline
title_short N-(2-Ferrocenylethyl­idene)-4-(trifluoro­meth­yl)aniline
title_sort n-(2-ferrocenylethyl­idene)-4-(trifluoro­meth­yl)aniline
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969081/
https://www.ncbi.nlm.nih.gov/pubmed/21582394
http://dx.doi.org/10.1107/S1600536809011039
work_keys_str_mv AT imhofwolfgang n2ferrocenylethylidene4trifluoromethylaniline

Ejemplares similares