Cargando…
N-(2,4-Dinitrophenyl)-N′-(1-p-tolylethylidene)hydrazine
In the title molecule, C(15)H(14)N(4)O(4), the dihedral angle between the two benzene rings is 2.21 (7)°. An intramolecular N—H⋯O hydrogen bond generates an S(6) ring motif. The mean planes of the ortho- and para-nitro groups make dihedral angles of 2.17 (17) and 2.05 (16)°, respectively, with the...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969085/ https://www.ncbi.nlm.nih.gov/pubmed/21582553 http://dx.doi.org/10.1107/S1600536809009957 |
Sumario: | In the title molecule, C(15)H(14)N(4)O(4), the dihedral angle between the two benzene rings is 2.21 (7)°. An intramolecular N—H⋯O hydrogen bond generates an S(6) ring motif. The mean planes of the ortho- and para-nitro groups make dihedral angles of 2.17 (17) and 2.05 (16)°, respectively, with the benzene ring to which they are attached. In the crystal structure, weak intermolecular C—H⋯O hydrogen bonds generate R (2) (2)(7), R (2) (2)(13) and R (2) (1)(10) ring motifs, linking symmetry-related molecules into extended chains along the b axis. In addition, there are intermolecular C⋯C [3.332 (2)–3.343 (2) Å] contacts which are shorter than the sum of the van der Waals radii. The crystal structure is further stabilized by intermolecular C—H⋯π and π–π stacking interactions [centroid–centroid distance = 3.8090 (9) Å]. |
---|