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N-(2,4-Dinitrophenyl)-N′-(1-p-tolylethylidene)hydrazine
In the title molecule, C(15)H(14)N(4)O(4), the dihedral angle between the two benzene rings is 2.21 (7)°. An intramolecular N—H⋯O hydrogen bond generates an S(6) ring motif. The mean planes of the ortho- and para-nitro groups make dihedral angles of 2.17 (17) and 2.05 (16)°, respectively, with the...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969085/ https://www.ncbi.nlm.nih.gov/pubmed/21582553 http://dx.doi.org/10.1107/S1600536809009957 |
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author | Kia, Reza Fun, Hoong-Kun Etemadi, Bijan Kargar, Hadi |
author_facet | Kia, Reza Fun, Hoong-Kun Etemadi, Bijan Kargar, Hadi |
author_sort | Kia, Reza |
collection | PubMed |
description | In the title molecule, C(15)H(14)N(4)O(4), the dihedral angle between the two benzene rings is 2.21 (7)°. An intramolecular N—H⋯O hydrogen bond generates an S(6) ring motif. The mean planes of the ortho- and para-nitro groups make dihedral angles of 2.17 (17) and 2.05 (16)°, respectively, with the benzene ring to which they are attached. In the crystal structure, weak intermolecular C—H⋯O hydrogen bonds generate R (2) (2)(7), R (2) (2)(13) and R (2) (1)(10) ring motifs, linking symmetry-related molecules into extended chains along the b axis. In addition, there are intermolecular C⋯C [3.332 (2)–3.343 (2) Å] contacts which are shorter than the sum of the van der Waals radii. The crystal structure is further stabilized by intermolecular C—H⋯π and π–π stacking interactions [centroid–centroid distance = 3.8090 (9) Å]. |
format | Text |
id | pubmed-2969085 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29690852010-12-30 N-(2,4-Dinitrophenyl)-N′-(1-p-tolylethylidene)hydrazine Kia, Reza Fun, Hoong-Kun Etemadi, Bijan Kargar, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(15)H(14)N(4)O(4), the dihedral angle between the two benzene rings is 2.21 (7)°. An intramolecular N—H⋯O hydrogen bond generates an S(6) ring motif. The mean planes of the ortho- and para-nitro groups make dihedral angles of 2.17 (17) and 2.05 (16)°, respectively, with the benzene ring to which they are attached. In the crystal structure, weak intermolecular C—H⋯O hydrogen bonds generate R (2) (2)(7), R (2) (2)(13) and R (2) (1)(10) ring motifs, linking symmetry-related molecules into extended chains along the b axis. In addition, there are intermolecular C⋯C [3.332 (2)–3.343 (2) Å] contacts which are shorter than the sum of the van der Waals radii. The crystal structure is further stabilized by intermolecular C—H⋯π and π–π stacking interactions [centroid–centroid distance = 3.8090 (9) Å]. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2969085/ /pubmed/21582553 http://dx.doi.org/10.1107/S1600536809009957 Text en © Kia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kia, Reza Fun, Hoong-Kun Etemadi, Bijan Kargar, Hadi N-(2,4-Dinitrophenyl)-N′-(1-p-tolylethylidene)hydrazine |
title |
N-(2,4-Dinitrophenyl)-N′-(1-p-tolylethylidene)hydrazine |
title_full |
N-(2,4-Dinitrophenyl)-N′-(1-p-tolylethylidene)hydrazine |
title_fullStr |
N-(2,4-Dinitrophenyl)-N′-(1-p-tolylethylidene)hydrazine |
title_full_unstemmed |
N-(2,4-Dinitrophenyl)-N′-(1-p-tolylethylidene)hydrazine |
title_short |
N-(2,4-Dinitrophenyl)-N′-(1-p-tolylethylidene)hydrazine |
title_sort | n-(2,4-dinitrophenyl)-n′-(1-p-tolylethylidene)hydrazine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969085/ https://www.ncbi.nlm.nih.gov/pubmed/21582553 http://dx.doi.org/10.1107/S1600536809009957 |
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