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{μ-1,3-Bis[(3,5-dimethyl­pyrazol-1-yl)meth­yl]benzene-κ(2) N (2):N (2′)}di-μ-chlorido-bis­[chloridopalladium(II)] toluene solvate

In the title complex, [Pd(2)Cl(4)(C(18)H(22)N(4))]·C(7)H(8), each of the two four-coordinated Pd(II) atoms is in a slightly distorted square-planar geometry, defined by one N atom from the ligand, two bridging Cl atoms and one terminal Cl atom. Inter­molecular C—H⋯π inter­actions between the pyrazol...

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Detalles Bibliográficos
Autores principales: Omondi, Bernard, Budhai, Asheena, Darkwa, James
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969090/
https://www.ncbi.nlm.nih.gov/pubmed/21582383
http://dx.doi.org/10.1107/S1600536809010629
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author Omondi, Bernard
Budhai, Asheena
Darkwa, James
author_facet Omondi, Bernard
Budhai, Asheena
Darkwa, James
author_sort Omondi, Bernard
collection PubMed
description In the title complex, [Pd(2)Cl(4)(C(18)H(22)N(4))]·C(7)H(8), each of the two four-coordinated Pd(II) atoms is in a slightly distorted square-planar geometry, defined by one N atom from the ligand, two bridging Cl atoms and one terminal Cl atom. Inter­molecular C—H⋯π inter­actions between the pyrazole ring H atom and the toluene ring stabilize the crystal structure.
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spelling pubmed-29690902010-12-30 {μ-1,3-Bis[(3,5-dimethyl­pyrazol-1-yl)meth­yl]benzene-κ(2) N (2):N (2′)}di-μ-chlorido-bis­[chloridopalladium(II)] toluene solvate Omondi, Bernard Budhai, Asheena Darkwa, James Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pd(2)Cl(4)(C(18)H(22)N(4))]·C(7)H(8), each of the two four-coordinated Pd(II) atoms is in a slightly distorted square-planar geometry, defined by one N atom from the ligand, two bridging Cl atoms and one terminal Cl atom. Inter­molecular C—H⋯π inter­actions between the pyrazole ring H atom and the toluene ring stabilize the crystal structure. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2969090/ /pubmed/21582383 http://dx.doi.org/10.1107/S1600536809010629 Text en © Omondi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Omondi, Bernard
Budhai, Asheena
Darkwa, James
{μ-1,3-Bis[(3,5-dimethyl­pyrazol-1-yl)meth­yl]benzene-κ(2) N (2):N (2′)}di-μ-chlorido-bis­[chloridopalladium(II)] toluene solvate
title {μ-1,3-Bis[(3,5-dimethyl­pyrazol-1-yl)meth­yl]benzene-κ(2) N (2):N (2′)}di-μ-chlorido-bis­[chloridopalladium(II)] toluene solvate
title_full {μ-1,3-Bis[(3,5-dimethyl­pyrazol-1-yl)meth­yl]benzene-κ(2) N (2):N (2′)}di-μ-chlorido-bis­[chloridopalladium(II)] toluene solvate
title_fullStr {μ-1,3-Bis[(3,5-dimethyl­pyrazol-1-yl)meth­yl]benzene-κ(2) N (2):N (2′)}di-μ-chlorido-bis­[chloridopalladium(II)] toluene solvate
title_full_unstemmed {μ-1,3-Bis[(3,5-dimethyl­pyrazol-1-yl)meth­yl]benzene-κ(2) N (2):N (2′)}di-μ-chlorido-bis­[chloridopalladium(II)] toluene solvate
title_short {μ-1,3-Bis[(3,5-dimethyl­pyrazol-1-yl)meth­yl]benzene-κ(2) N (2):N (2′)}di-μ-chlorido-bis­[chloridopalladium(II)] toluene solvate
title_sort {μ-1,3-bis[(3,5-dimethyl­pyrazol-1-yl)meth­yl]benzene-κ(2) n (2):n (2′)}di-μ-chlorido-bis­[chloridopalladium(ii)] toluene solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969090/
https://www.ncbi.nlm.nih.gov/pubmed/21582383
http://dx.doi.org/10.1107/S1600536809010629
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