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{μ-1,3-Bis[(3,5-dimethylpyrazol-1-yl)methyl]benzene-κ(2) N (2):N (2′)}di-μ-chlorido-bis[chloridopalladium(II)] toluene solvate
In the title complex, [Pd(2)Cl(4)(C(18)H(22)N(4))]·C(7)H(8), each of the two four-coordinated Pd(II) atoms is in a slightly distorted square-planar geometry, defined by one N atom from the ligand, two bridging Cl atoms and one terminal Cl atom. Intermolecular C—H⋯π interactions between the pyrazol...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969090/ https://www.ncbi.nlm.nih.gov/pubmed/21582383 http://dx.doi.org/10.1107/S1600536809010629 |
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author | Omondi, Bernard Budhai, Asheena Darkwa, James |
author_facet | Omondi, Bernard Budhai, Asheena Darkwa, James |
author_sort | Omondi, Bernard |
collection | PubMed |
description | In the title complex, [Pd(2)Cl(4)(C(18)H(22)N(4))]·C(7)H(8), each of the two four-coordinated Pd(II) atoms is in a slightly distorted square-planar geometry, defined by one N atom from the ligand, two bridging Cl atoms and one terminal Cl atom. Intermolecular C—H⋯π interactions between the pyrazole ring H atom and the toluene ring stabilize the crystal structure. |
format | Text |
id | pubmed-2969090 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29690902010-12-30 {μ-1,3-Bis[(3,5-dimethylpyrazol-1-yl)methyl]benzene-κ(2) N (2):N (2′)}di-μ-chlorido-bis[chloridopalladium(II)] toluene solvate Omondi, Bernard Budhai, Asheena Darkwa, James Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pd(2)Cl(4)(C(18)H(22)N(4))]·C(7)H(8), each of the two four-coordinated Pd(II) atoms is in a slightly distorted square-planar geometry, defined by one N atom from the ligand, two bridging Cl atoms and one terminal Cl atom. Intermolecular C—H⋯π interactions between the pyrazole ring H atom and the toluene ring stabilize the crystal structure. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2969090/ /pubmed/21582383 http://dx.doi.org/10.1107/S1600536809010629 Text en © Omondi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Omondi, Bernard Budhai, Asheena Darkwa, James {μ-1,3-Bis[(3,5-dimethylpyrazol-1-yl)methyl]benzene-κ(2) N (2):N (2′)}di-μ-chlorido-bis[chloridopalladium(II)] toluene solvate |
title | {μ-1,3-Bis[(3,5-dimethylpyrazol-1-yl)methyl]benzene-κ(2)
N
(2):N
(2′)}di-μ-chlorido-bis[chloridopalladium(II)] toluene solvate |
title_full | {μ-1,3-Bis[(3,5-dimethylpyrazol-1-yl)methyl]benzene-κ(2)
N
(2):N
(2′)}di-μ-chlorido-bis[chloridopalladium(II)] toluene solvate |
title_fullStr | {μ-1,3-Bis[(3,5-dimethylpyrazol-1-yl)methyl]benzene-κ(2)
N
(2):N
(2′)}di-μ-chlorido-bis[chloridopalladium(II)] toluene solvate |
title_full_unstemmed | {μ-1,3-Bis[(3,5-dimethylpyrazol-1-yl)methyl]benzene-κ(2)
N
(2):N
(2′)}di-μ-chlorido-bis[chloridopalladium(II)] toluene solvate |
title_short | {μ-1,3-Bis[(3,5-dimethylpyrazol-1-yl)methyl]benzene-κ(2)
N
(2):N
(2′)}di-μ-chlorido-bis[chloridopalladium(II)] toluene solvate |
title_sort | {μ-1,3-bis[(3,5-dimethylpyrazol-1-yl)methyl]benzene-κ(2)
n
(2):n
(2′)}di-μ-chlorido-bis[chloridopalladium(ii)] toluene solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969090/ https://www.ncbi.nlm.nih.gov/pubmed/21582383 http://dx.doi.org/10.1107/S1600536809010629 |
work_keys_str_mv | AT omondibernard m13bis35dimethylpyrazol1ylmethylbenzenek2n2n2dimchloridobischloridopalladiumiitoluenesolvate AT budhaiasheena m13bis35dimethylpyrazol1ylmethylbenzenek2n2n2dimchloridobischloridopalladiumiitoluenesolvate AT darkwajames m13bis35dimethylpyrazol1ylmethylbenzenek2n2n2dimchloridobischloridopalladiumiitoluenesolvate |