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6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol

In the crystal structure, the title Schiff base compound, C(23)H(30)N(2)O(4), exhibits crystallographic twofold rotation symmetry. The imino group is coplanar with the aromatic ring with an N—C—C—C torsion angle of -179.72 (9)°. An intra­molecular O—H⋯N hydrogen bond forms a six-membered ring, produ...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Kargar, Hadi, Kia, Reza, Jamshidvand, Arezoo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969095/
https://www.ncbi.nlm.nih.gov/pubmed/21582445
http://dx.doi.org/10.1107/S1600536809007557
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author Fun, Hoong-Kun
Kargar, Hadi
Kia, Reza
Jamshidvand, Arezoo
author_facet Fun, Hoong-Kun
Kargar, Hadi
Kia, Reza
Jamshidvand, Arezoo
author_sort Fun, Hoong-Kun
collection PubMed
description In the crystal structure, the title Schiff base compound, C(23)H(30)N(2)O(4), exhibits crystallographic twofold rotation symmetry. The imino group is coplanar with the aromatic ring with an N—C—C—C torsion angle of -179.72 (9)°. An intra­molecular O—H⋯N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The dihedral angle between symmetry related benzene rings is 28.05 (5)°. The eth­oxy group makes a C—O—C—C torsion angle of −7.20 (16)° with the benzene ring. The crystal structure is stabilized by inter­molecular C—H⋯π inter­actions.
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spelling pubmed-29690952010-12-30 6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol Fun, Hoong-Kun Kargar, Hadi Kia, Reza Jamshidvand, Arezoo Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure, the title Schiff base compound, C(23)H(30)N(2)O(4), exhibits crystallographic twofold rotation symmetry. The imino group is coplanar with the aromatic ring with an N—C—C—C torsion angle of -179.72 (9)°. An intra­molecular O—H⋯N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The dihedral angle between symmetry related benzene rings is 28.05 (5)°. The eth­oxy group makes a C—O—C—C torsion angle of −7.20 (16)° with the benzene ring. The crystal structure is stabilized by inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2969095/ /pubmed/21582445 http://dx.doi.org/10.1107/S1600536809007557 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Kargar, Hadi
Kia, Reza
Jamshidvand, Arezoo
6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol
title 6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol
title_full 6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol
title_fullStr 6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol
title_full_unstemmed 6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol
title_short 6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol
title_sort 6,6′-diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969095/
https://www.ncbi.nlm.nih.gov/pubmed/21582445
http://dx.doi.org/10.1107/S1600536809007557
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