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6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol
In the crystal structure, the title Schiff base compound, C(23)H(30)N(2)O(4), exhibits crystallographic twofold rotation symmetry. The imino group is coplanar with the aromatic ring with an N—C—C—C torsion angle of -179.72 (9)°. An intramolecular O—H⋯N hydrogen bond forms a six-membered ring, produ...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969095/ https://www.ncbi.nlm.nih.gov/pubmed/21582445 http://dx.doi.org/10.1107/S1600536809007557 |
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author | Fun, Hoong-Kun Kargar, Hadi Kia, Reza Jamshidvand, Arezoo |
author_facet | Fun, Hoong-Kun Kargar, Hadi Kia, Reza Jamshidvand, Arezoo |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the crystal structure, the title Schiff base compound, C(23)H(30)N(2)O(4), exhibits crystallographic twofold rotation symmetry. The imino group is coplanar with the aromatic ring with an N—C—C—C torsion angle of -179.72 (9)°. An intramolecular O—H⋯N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The dihedral angle between symmetry related benzene rings is 28.05 (5)°. The ethoxy group makes a C—O—C—C torsion angle of −7.20 (16)° with the benzene ring. The crystal structure is stabilized by intermolecular C—H⋯π interactions. |
format | Text |
id | pubmed-2969095 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29690952010-12-30 6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol Fun, Hoong-Kun Kargar, Hadi Kia, Reza Jamshidvand, Arezoo Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure, the title Schiff base compound, C(23)H(30)N(2)O(4), exhibits crystallographic twofold rotation symmetry. The imino group is coplanar with the aromatic ring with an N—C—C—C torsion angle of -179.72 (9)°. An intramolecular O—H⋯N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The dihedral angle between symmetry related benzene rings is 28.05 (5)°. The ethoxy group makes a C—O—C—C torsion angle of −7.20 (16)° with the benzene ring. The crystal structure is stabilized by intermolecular C—H⋯π interactions. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2969095/ /pubmed/21582445 http://dx.doi.org/10.1107/S1600536809007557 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Kargar, Hadi Kia, Reza Jamshidvand, Arezoo 6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title | 6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title_full | 6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title_fullStr | 6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title_full_unstemmed | 6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title_short | 6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title_sort | 6,6′-diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969095/ https://www.ncbi.nlm.nih.gov/pubmed/21582445 http://dx.doi.org/10.1107/S1600536809007557 |
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