9-(Biphenyl-4-yl­oxycarbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate

In the crystal structure of the title compound, C(27)H(20)NO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through π–π inter­actions between the acridine ring systems [centroid-centroid distances = 3.668 (2)–3.994 (2) Å]. These dimers are further linked by C—H⋯O and C—H⋯π inter­actions. T...

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Detalles Bibliográficos
Autores principales: Trzybiński, Damian, Skupień, Magdalena, Krzymiński, Karol, Sikorski, Artur, Błażejowski, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969101/
https://www.ncbi.nlm.nih.gov/pubmed/21582498
http://dx.doi.org/10.1107/S1600536809007569
Descripción
Sumario:In the crystal structure of the title compound, C(27)H(20)NO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through π–π inter­actions between the acridine ring systems [centroid-centroid distances = 3.668 (2)–3.994 (2) Å]. These dimers are further linked by C—H⋯O and C—H⋯π inter­actions. The cation and the anion are connected by C—H⋯O inter­actions. The mean plane of the acridine ring system makes dihedral angles of 10.6 (1) and 82.5 (1)°, respectively, with the adjacent phenyl ring and the carb­oxy group. The two phenyl rings of the biphenyl group are oriented at 42.9 (1)°.

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