9-(Biphenyl-4-yl­oxycarbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate

In the crystal structure of the title compound, C(27)H(20)NO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through π–π inter­actions between the acridine ring systems [centroid-centroid distances = 3.668 (2)–3.994 (2) Å]. These dimers are further linked by C—H⋯O and C—H⋯π inter­actions. T...

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Autores principales: Trzybiński, Damian, Skupień, Magdalena, Krzymiński, Karol, Sikorski, Artur, Błażejowski, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969101/
https://www.ncbi.nlm.nih.gov/pubmed/21582498
http://dx.doi.org/10.1107/S1600536809007569
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author Trzybiński, Damian
Skupień, Magdalena
Krzymiński, Karol
Sikorski, Artur
Błażejowski, Jerzy
author_facet Trzybiński, Damian
Skupień, Magdalena
Krzymiński, Karol
Sikorski, Artur
Błażejowski, Jerzy
author_sort Trzybiński, Damian
collection PubMed
description In the crystal structure of the title compound, C(27)H(20)NO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through π–π inter­actions between the acridine ring systems [centroid-centroid distances = 3.668 (2)–3.994 (2) Å]. These dimers are further linked by C—H⋯O and C—H⋯π inter­actions. The cation and the anion are connected by C—H⋯O inter­actions. The mean plane of the acridine ring system makes dihedral angles of 10.6 (1) and 82.5 (1)°, respectively, with the adjacent phenyl ring and the carb­oxy group. The two phenyl rings of the biphenyl group are oriented at 42.9 (1)°.
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spelling pubmed-29691012010-12-30 9-(Biphenyl-4-yl­oxycarbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate Trzybiński, Damian Skupień, Magdalena Krzymiński, Karol Sikorski, Artur Błażejowski, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(27)H(20)NO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through π–π inter­actions between the acridine ring systems [centroid-centroid distances = 3.668 (2)–3.994 (2) Å]. These dimers are further linked by C—H⋯O and C—H⋯π inter­actions. The cation and the anion are connected by C—H⋯O inter­actions. The mean plane of the acridine ring system makes dihedral angles of 10.6 (1) and 82.5 (1)°, respectively, with the adjacent phenyl ring and the carb­oxy group. The two phenyl rings of the biphenyl group are oriented at 42.9 (1)°. International Union of Crystallography 2009-03-14 /pmc/articles/PMC2969101/ /pubmed/21582498 http://dx.doi.org/10.1107/S1600536809007569 Text en © Trzybiński et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Trzybiński, Damian
Skupień, Magdalena
Krzymiński, Karol
Sikorski, Artur
Błażejowski, Jerzy
9-(Biphenyl-4-yl­oxycarbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title 9-(Biphenyl-4-yl­oxycarbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_full 9-(Biphenyl-4-yl­oxycarbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_fullStr 9-(Biphenyl-4-yl­oxycarbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_full_unstemmed 9-(Biphenyl-4-yl­oxycarbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_short 9-(Biphenyl-4-yl­oxycarbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_sort 9-(biphenyl-4-yl­oxycarbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969101/
https://www.ncbi.nlm.nih.gov/pubmed/21582498
http://dx.doi.org/10.1107/S1600536809007569
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AT krzyminskikarol 9biphenyl4yloxycarbonyl10methylacridiniumtrifluoromethanesulfonate
AT sikorskiartur 9biphenyl4yloxycarbonyl10methylacridiniumtrifluoromethanesulfonate
AT błazejowskijerzy 9biphenyl4yloxycarbonyl10methylacridiniumtrifluoromethanesulfonate

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