{6,6′-Dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II) monohydrate

The mol­ecule of the title compound, [Zn(C(20)H(22)N(2)O(4))]·H(2)O, deviates from planarity with a dihedral angle between the two benzene rings is 18.3 (1)°. The four-coordinate Zn(II) ion has a distorted square-planar coordination and is N(2)O(2)-chelated by the Schiff base ligand. The Zn(II) ion...

Descripción completa

Detalles Bibliográficos
Autores principales: Shen, Yong-Miao, Wang, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969102/
https://www.ncbi.nlm.nih.gov/pubmed/21582381
http://dx.doi.org/10.1107/S1600536809010344
_version_ 1782190066194448384
author Shen, Yong-Miao
Wang, Wei
author_facet Shen, Yong-Miao
Wang, Wei
author_sort Shen, Yong-Miao
collection PubMed
description The mol­ecule of the title compound, [Zn(C(20)H(22)N(2)O(4))]·H(2)O, deviates from planarity with a dihedral angle between the two benzene rings is 18.3 (1)°. The four-coordinate Zn(II) ion has a distorted square-planar coordination and is N(2)O(2)-chelated by the Schiff base ligand. The Zn(II) ion and solvent water mol­ecule are located on a twofold rotation axis. The structure displays inter­molecular O—H⋯O hydrogen bonding.
format Text
id pubmed-2969102
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29691022010-12-30 {6,6′-Dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II) monohydrate Shen, Yong-Miao Wang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecule of the title compound, [Zn(C(20)H(22)N(2)O(4))]·H(2)O, deviates from planarity with a dihedral angle between the two benzene rings is 18.3 (1)°. The four-coordinate Zn(II) ion has a distorted square-planar coordination and is N(2)O(2)-chelated by the Schiff base ligand. The Zn(II) ion and solvent water mol­ecule are located on a twofold rotation axis. The structure displays inter­molecular O—H⋯O hydrogen bonding. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2969102/ /pubmed/21582381 http://dx.doi.org/10.1107/S1600536809010344 Text en © Shen and Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shen, Yong-Miao
Wang, Wei
{6,6′-Dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II) monohydrate
title {6,6′-Dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II) monohydrate
title_full {6,6′-Dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II) monohydrate
title_fullStr {6,6′-Dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II) monohydrate
title_full_unstemmed {6,6′-Dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II) monohydrate
title_short {6,6′-Dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II) monohydrate
title_sort {6,6′-dieth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969102/
https://www.ncbi.nlm.nih.gov/pubmed/21582381
http://dx.doi.org/10.1107/S1600536809010344
work_keys_str_mv AT shenyongmiao 66diethoxy22ethane12diylbisnitrilomethylidynediphenolatozinciimonohydrate
AT wangwei 66diethoxy22ethane12diylbisnitrilomethylidynediphenolatozinciimonohydrate

Ejemplares similares