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Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)neodymium(III)silver(I)] monohydrate]

In the title coordination polymer, {[AgNd(C(5)H(3)N(2)O(2))(2)(C(2)O(4))]·H(2)O}(n), the Nd(III) atom is coordinated in a distorted monocapped square-anti­prismatic geometry by two O and two N atoms of two N,O-bidentate pyrazine-2-carboxyl­ate (2-pzc) ligands, four O atoms of two bidentate oxalate l...

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Detalles Bibliográficos
Autores principales: Feng, Tian-Jun, Wen, Yan-Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969187/
https://www.ncbi.nlm.nih.gov/pubmed/21582751
http://dx.doi.org/10.1107/S160053680902128X
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author Feng, Tian-Jun
Wen, Yan-Mei
author_facet Feng, Tian-Jun
Wen, Yan-Mei
author_sort Feng, Tian-Jun
collection PubMed
description In the title coordination polymer, {[AgNd(C(5)H(3)N(2)O(2))(2)(C(2)O(4))]·H(2)O}(n), the Nd(III) atom is coordinated in a distorted monocapped square-anti­prismatic geometry by two O and two N atoms of two N,O-bidentate pyrazine-2-carboxyl­ate (2-pzc) ligands, four O atoms of two bidentate oxalate ligands, and one O atom of a monodentate carboxyl­ate group of a 2-pzc ligand. The Ag(I) ion is coordinated in a distorted tetra­hedral geometry by two N atoms from two monodentate 2-pzc ligands, one O atom from one monodentate oxalate ligand and one O atom of a bridging carboxyl­ate group of a 2-pzc ligand. The oxalate anions link neighbouring neodymium(III) metal centres into Nd–oxalate chains, which are inter­connected by Ag(2-pyz)(2) units, forming a three-dimensional polymeric framework. Inter­molecular O—H⋯O and C—H⋯O hydrogen bonds are observed in the crystal structure.
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spelling pubmed-29691872010-12-30 Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)neodymium(III)silver(I)] monohydrate] Feng, Tian-Jun Wen, Yan-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[AgNd(C(5)H(3)N(2)O(2))(2)(C(2)O(4))]·H(2)O}(n), the Nd(III) atom is coordinated in a distorted monocapped square-anti­prismatic geometry by two O and two N atoms of two N,O-bidentate pyrazine-2-carboxyl­ate (2-pzc) ligands, four O atoms of two bidentate oxalate ligands, and one O atom of a monodentate carboxyl­ate group of a 2-pzc ligand. The Ag(I) ion is coordinated in a distorted tetra­hedral geometry by two N atoms from two monodentate 2-pzc ligands, one O atom from one monodentate oxalate ligand and one O atom of a bridging carboxyl­ate group of a 2-pzc ligand. The oxalate anions link neighbouring neodymium(III) metal centres into Nd–oxalate chains, which are inter­connected by Ag(2-pyz)(2) units, forming a three-dimensional polymeric framework. Inter­molecular O—H⋯O and C—H⋯O hydrogen bonds are observed in the crystal structure. International Union of Crystallography 2009-06-27 /pmc/articles/PMC2969187/ /pubmed/21582751 http://dx.doi.org/10.1107/S160053680902128X Text en © Feng and Wen 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Feng, Tian-Jun
Wen, Yan-Mei
Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)neodymium(III)silver(I)] monohydrate]
title Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)neodymium(III)silver(I)] monohydrate]
title_full Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)neodymium(III)silver(I)] monohydrate]
title_fullStr Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)neodymium(III)silver(I)] monohydrate]
title_full_unstemmed Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)neodymium(III)silver(I)] monohydrate]
title_short Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)neodymium(III)silver(I)] monohydrate]
title_sort poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)neodymium(iii)silver(i)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969187/
https://www.ncbi.nlm.nih.gov/pubmed/21582751
http://dx.doi.org/10.1107/S160053680902128X
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