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Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)neodymium(III)silver(I)] monohydrate]
In the title coordination polymer, {[AgNd(C(5)H(3)N(2)O(2))(2)(C(2)O(4))]·H(2)O}(n), the Nd(III) atom is coordinated in a distorted monocapped square-antiprismatic geometry by two O and two N atoms of two N,O-bidentate pyrazine-2-carboxylate (2-pzc) ligands, four O atoms of two bidentate oxalate l...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969187/ https://www.ncbi.nlm.nih.gov/pubmed/21582751 http://dx.doi.org/10.1107/S160053680902128X |
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author | Feng, Tian-Jun Wen, Yan-Mei |
author_facet | Feng, Tian-Jun Wen, Yan-Mei |
author_sort | Feng, Tian-Jun |
collection | PubMed |
description | In the title coordination polymer, {[AgNd(C(5)H(3)N(2)O(2))(2)(C(2)O(4))]·H(2)O}(n), the Nd(III) atom is coordinated in a distorted monocapped square-antiprismatic geometry by two O and two N atoms of two N,O-bidentate pyrazine-2-carboxylate (2-pzc) ligands, four O atoms of two bidentate oxalate ligands, and one O atom of a monodentate carboxylate group of a 2-pzc ligand. The Ag(I) ion is coordinated in a distorted tetrahedral geometry by two N atoms from two monodentate 2-pzc ligands, one O atom from one monodentate oxalate ligand and one O atom of a bridging carboxylate group of a 2-pzc ligand. The oxalate anions link neighbouring neodymium(III) metal centres into Nd–oxalate chains, which are interconnected by Ag(2-pyz)(2) units, forming a three-dimensional polymeric framework. Intermolecular O—H⋯O and C—H⋯O hydrogen bonds are observed in the crystal structure. |
format | Text |
id | pubmed-2969187 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29691872010-12-30 Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)neodymium(III)silver(I)] monohydrate] Feng, Tian-Jun Wen, Yan-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[AgNd(C(5)H(3)N(2)O(2))(2)(C(2)O(4))]·H(2)O}(n), the Nd(III) atom is coordinated in a distorted monocapped square-antiprismatic geometry by two O and two N atoms of two N,O-bidentate pyrazine-2-carboxylate (2-pzc) ligands, four O atoms of two bidentate oxalate ligands, and one O atom of a monodentate carboxylate group of a 2-pzc ligand. The Ag(I) ion is coordinated in a distorted tetrahedral geometry by two N atoms from two monodentate 2-pzc ligands, one O atom from one monodentate oxalate ligand and one O atom of a bridging carboxylate group of a 2-pzc ligand. The oxalate anions link neighbouring neodymium(III) metal centres into Nd–oxalate chains, which are interconnected by Ag(2-pyz)(2) units, forming a three-dimensional polymeric framework. Intermolecular O—H⋯O and C—H⋯O hydrogen bonds are observed in the crystal structure. International Union of Crystallography 2009-06-27 /pmc/articles/PMC2969187/ /pubmed/21582751 http://dx.doi.org/10.1107/S160053680902128X Text en © Feng and Wen 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Feng, Tian-Jun Wen, Yan-Mei Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)neodymium(III)silver(I)] monohydrate] |
title | Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)neodymium(III)silver(I)] monohydrate] |
title_full | Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)neodymium(III)silver(I)] monohydrate] |
title_fullStr | Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)neodymium(III)silver(I)] monohydrate] |
title_full_unstemmed | Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)neodymium(III)silver(I)] monohydrate] |
title_short | Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)neodymium(III)silver(I)] monohydrate] |
title_sort | poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)neodymium(iii)silver(i)] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969187/ https://www.ncbi.nlm.nih.gov/pubmed/21582751 http://dx.doi.org/10.1107/S160053680902128X |
work_keys_str_mv | AT fengtianjun polyhemim4oxalatohemim2oxalatobism3pyrazine2carboxylatoneodymiumiiisilverimonohydrate AT wenyanmei polyhemim4oxalatohemim2oxalatobism3pyrazine2carboxylatoneodymiumiiisilverimonohydrate |