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Dihydronium hexakis[bromido/chlorido(0.75/0.25)]dicadmate(II)–triphenylphosphine oxide (1/6)
In the salt, (H(3)O)(2)[Cd(2)Br(4.5)Cl(1.5)]·6C(18)H(15)OP, the hydronium cation forms short O—H⋯O hydrogen bonds to the O atoms of the triphenylphosphine oxide units. The centrosymmetric dinuclear anion has two halide atoms functioning in a bridging mode, which confers tetrahedral coordination t...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969192/ https://www.ncbi.nlm.nih.gov/pubmed/21582664 http://dx.doi.org/10.1107/S1600536809020388 |
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| author | Lo, Kong Mun Ng, Seik Weng |
| author_facet | Lo, Kong Mun Ng, Seik Weng |
| author_sort | Lo, Kong Mun |
| collection | PubMed |
| description | In the salt, (H(3)O)(2)[Cd(2)Br(4.5)Cl(1.5)]·6C(18)H(15)OP, the hydronium cation forms short O—H⋯O hydrogen bonds to the O atoms of the triphenylphosphine oxide units. The centrosymmetric dinuclear anion has two halide atoms functioning in a bridging mode, which confers tetrahedral coordination to the Cd atom. The three independent halide atoms are each a mixture of bromide and chloride; the occupancies of the Br atoms are 0.6434 (11), 0.7468 (11) and 0.8598 (11). |
| format | Text |
| id | pubmed-2969192 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29691922010-12-30 Dihydronium hexakis[bromido/chlorido(0.75/0.25)]dicadmate(II)–triphenylphosphine oxide (1/6) Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the salt, (H(3)O)(2)[Cd(2)Br(4.5)Cl(1.5)]·6C(18)H(15)OP, the hydronium cation forms short O—H⋯O hydrogen bonds to the O atoms of the triphenylphosphine oxide units. The centrosymmetric dinuclear anion has two halide atoms functioning in a bridging mode, which confers tetrahedral coordination to the Cd atom. The three independent halide atoms are each a mixture of bromide and chloride; the occupancies of the Br atoms are 0.6434 (11), 0.7468 (11) and 0.8598 (11). International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969192/ /pubmed/21582664 http://dx.doi.org/10.1107/S1600536809020388 Text en © Lo and Ng 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lo, Kong Mun Ng, Seik Weng Dihydronium hexakis[bromido/chlorido(0.75/0.25)]dicadmate(II)–triphenylphosphine oxide (1/6) |
| title | Dihydronium hexakis[bromido/chlorido(0.75/0.25)]dicadmate(II)–triphenylphosphine oxide (1/6) |
| title_full | Dihydronium hexakis[bromido/chlorido(0.75/0.25)]dicadmate(II)–triphenylphosphine oxide (1/6) |
| title_fullStr | Dihydronium hexakis[bromido/chlorido(0.75/0.25)]dicadmate(II)–triphenylphosphine oxide (1/6) |
| title_full_unstemmed | Dihydronium hexakis[bromido/chlorido(0.75/0.25)]dicadmate(II)–triphenylphosphine oxide (1/6) |
| title_short | Dihydronium hexakis[bromido/chlorido(0.75/0.25)]dicadmate(II)–triphenylphosphine oxide (1/6) |
| title_sort | dihydronium hexakis[bromido/chlorido(0.75/0.25)]dicadmate(ii)–triphenylphosphine oxide (1/6) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969192/ https://www.ncbi.nlm.nih.gov/pubmed/21582664 http://dx.doi.org/10.1107/S1600536809020388 |
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