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2-[(E)-2-(4-Chlorophenyl)ethenyl]-1-methylpyridinium 4-methoxybenzenesulfonate
In the asymmetric unit of the title salt, C(14)H(13)ClN(+)·C(7)H(7)O(4)S(−), there are two crystallographically independent molecules for each component. Each cation adopts an E configuration with respect to the C=C bond and is slightly twisted; the dihedral angle between the pyridinium and benzene...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969195/ https://www.ncbi.nlm.nih.gov/pubmed/21582835 http://dx.doi.org/10.1107/S1600536809021679 |
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author | Chanawanno, Kullapa Chantrapromma, Suchada Fun, Hoong-Kun |
author_facet | Chanawanno, Kullapa Chantrapromma, Suchada Fun, Hoong-Kun |
author_sort | Chanawanno, Kullapa |
collection | PubMed |
description | In the asymmetric unit of the title salt, C(14)H(13)ClN(+)·C(7)H(7)O(4)S(−), there are two crystallographically independent molecules for each component. Each cation adopts an E configuration with respect to the C=C bond and is slightly twisted; the dihedral angle between the pyridinium and benzene rings is 6.53 (7)° for one molecule and 5.30 (7)° for the other. The methoxy groups in the anion molecules are each twisted from the mean plane of benzene ring with torsion angles of 16.38 (19) and 4.32 (19)°. In the crystal structure, the cations are stacked in an antiparallel manner along the a axis and the anions are linked together by C—H⋯O interactions into a layer parallel to (001). The anion layers are further linked to adjacent cations by C—H⋯O interactions. C—H⋯π interactions involving the benzene rings of both ions are also observed. |
format | Text |
id | pubmed-2969195 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29691952010-12-30 2-[(E)-2-(4-Chlorophenyl)ethenyl]-1-methylpyridinium 4-methoxybenzenesulfonate Chanawanno, Kullapa Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the asymmetric unit of the title salt, C(14)H(13)ClN(+)·C(7)H(7)O(4)S(−), there are two crystallographically independent molecules for each component. Each cation adopts an E configuration with respect to the C=C bond and is slightly twisted; the dihedral angle between the pyridinium and benzene rings is 6.53 (7)° for one molecule and 5.30 (7)° for the other. The methoxy groups in the anion molecules are each twisted from the mean plane of benzene ring with torsion angles of 16.38 (19) and 4.32 (19)°. In the crystal structure, the cations are stacked in an antiparallel manner along the a axis and the anions are linked together by C—H⋯O interactions into a layer parallel to (001). The anion layers are further linked to adjacent cations by C—H⋯O interactions. C—H⋯π interactions involving the benzene rings of both ions are also observed. International Union of Crystallography 2009-06-10 /pmc/articles/PMC2969195/ /pubmed/21582835 http://dx.doi.org/10.1107/S1600536809021679 Text en © Chanawanno et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chanawanno, Kullapa Chantrapromma, Suchada Fun, Hoong-Kun 2-[(E)-2-(4-Chlorophenyl)ethenyl]-1-methylpyridinium 4-methoxybenzenesulfonate |
title | 2-[(E)-2-(4-Chlorophenyl)ethenyl]-1-methylpyridinium 4-methoxybenzenesulfonate |
title_full | 2-[(E)-2-(4-Chlorophenyl)ethenyl]-1-methylpyridinium 4-methoxybenzenesulfonate |
title_fullStr | 2-[(E)-2-(4-Chlorophenyl)ethenyl]-1-methylpyridinium 4-methoxybenzenesulfonate |
title_full_unstemmed | 2-[(E)-2-(4-Chlorophenyl)ethenyl]-1-methylpyridinium 4-methoxybenzenesulfonate |
title_short | 2-[(E)-2-(4-Chlorophenyl)ethenyl]-1-methylpyridinium 4-methoxybenzenesulfonate |
title_sort | 2-[(e)-2-(4-chlorophenyl)ethenyl]-1-methylpyridinium 4-methoxybenzenesulfonate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969195/ https://www.ncbi.nlm.nih.gov/pubmed/21582835 http://dx.doi.org/10.1107/S1600536809021679 |
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