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2-[(E)-2-(4-Chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-methoxy­benzene­sulfonate

In the asymmetric unit of the title salt, C(14)H(13)ClN(+)·C(7)H(7)O(4)S(−), there are two crystallographically independent mol­ecules for each component. Each cation adopts an E configuration with respect to the C=C bond and is slightly twisted; the dihedral angle between the pyridinium and benzene...

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Autores principales: Chanawanno, Kullapa, Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969195/
https://www.ncbi.nlm.nih.gov/pubmed/21582835
http://dx.doi.org/10.1107/S1600536809021679
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author Chanawanno, Kullapa
Chantrapromma, Suchada
Fun, Hoong-Kun
author_facet Chanawanno, Kullapa
Chantrapromma, Suchada
Fun, Hoong-Kun
author_sort Chanawanno, Kullapa
collection PubMed
description In the asymmetric unit of the title salt, C(14)H(13)ClN(+)·C(7)H(7)O(4)S(−), there are two crystallographically independent mol­ecules for each component. Each cation adopts an E configuration with respect to the C=C bond and is slightly twisted; the dihedral angle between the pyridinium and benzene rings is 6.53 (7)° for one mol­ecule and 5.30 (7)° for the other. The meth­oxy groups in the anion mol­ecules are each twisted from the mean plane of benzene ring with torsion angles of 16.38 (19) and 4.32 (19)°. In the crystal structure, the cations are stacked in an anti­parallel manner along the a axis and the anions are linked together by C—H⋯O inter­actions into a layer parallel to (001). The anion layers are further linked to adjacent cations by C—H⋯O inter­actions. C—H⋯π inter­actions involving the benzene rings of both ions are also observed.
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spelling pubmed-29691952010-12-30 2-[(E)-2-(4-Chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-methoxy­benzene­sulfonate Chanawanno, Kullapa Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the asymmetric unit of the title salt, C(14)H(13)ClN(+)·C(7)H(7)O(4)S(−), there are two crystallographically independent mol­ecules for each component. Each cation adopts an E configuration with respect to the C=C bond and is slightly twisted; the dihedral angle between the pyridinium and benzene rings is 6.53 (7)° for one mol­ecule and 5.30 (7)° for the other. The meth­oxy groups in the anion mol­ecules are each twisted from the mean plane of benzene ring with torsion angles of 16.38 (19) and 4.32 (19)°. In the crystal structure, the cations are stacked in an anti­parallel manner along the a axis and the anions are linked together by C—H⋯O inter­actions into a layer parallel to (001). The anion layers are further linked to adjacent cations by C—H⋯O inter­actions. C—H⋯π inter­actions involving the benzene rings of both ions are also observed. International Union of Crystallography 2009-06-10 /pmc/articles/PMC2969195/ /pubmed/21582835 http://dx.doi.org/10.1107/S1600536809021679 Text en © Chanawanno et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chanawanno, Kullapa
Chantrapromma, Suchada
Fun, Hoong-Kun
2-[(E)-2-(4-Chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-methoxy­benzene­sulfonate
title 2-[(E)-2-(4-Chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-methoxy­benzene­sulfonate
title_full 2-[(E)-2-(4-Chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-methoxy­benzene­sulfonate
title_fullStr 2-[(E)-2-(4-Chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-methoxy­benzene­sulfonate
title_full_unstemmed 2-[(E)-2-(4-Chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-methoxy­benzene­sulfonate
title_short 2-[(E)-2-(4-Chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-methoxy­benzene­sulfonate
title_sort 2-[(e)-2-(4-chloro­phen­yl)ethen­yl]-1-methyl­pyridinium 4-methoxy­benzene­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969195/
https://www.ncbi.nlm.nih.gov/pubmed/21582835
http://dx.doi.org/10.1107/S1600536809021679
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