trans-Diaqua­bis[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ido-κ(2) N (3),O (4)]iron(II)

In the title complex, [Fe(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], the Fe(II) atom is located on a twofold rotation axis and is coordinated by two trans-positioned N,O-bidentate and zwitterionic 5-carboxy-2-(pyridinium-4-yl)-1H-imidazol-1-ide-4-carboxylate H(2)PIDC(−) ligands and two water mol­ecules in a...

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Detalles Bibliográficos
Autores principales: Li, Xia, Liu, Wei, Wu, Ben-Lai, Zhang, Hong-Yun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969200/
https://www.ncbi.nlm.nih.gov/pubmed/21582742
http://dx.doi.org/10.1107/S160053680902337X
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author Li, Xia
Liu, Wei
Wu, Ben-Lai
Zhang, Hong-Yun
author_facet Li, Xia
Liu, Wei
Wu, Ben-Lai
Zhang, Hong-Yun
author_sort Li, Xia
collection PubMed
description In the title complex, [Fe(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], the Fe(II) atom is located on a twofold rotation axis and is coordinated by two trans-positioned N,O-bidentate and zwitterionic 5-carboxy-2-(pyridinium-4-yl)-1H-imidazol-1-ide-4-carboxylate H(2)PIDC(−) ligands and two water mol­ecules in a distorted environment. In the crystal packing, a three-dimensional network is constructed via hydrogen-bonding involving the water mol­ecules, uncoordinated imidazole N atom, protonated pyridine N and carboxyl­ate O atoms.
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spelling pubmed-29692002010-12-30 trans-Diaqua­bis[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ido-κ(2) N (3),O (4)]iron(II) Li, Xia Liu, Wei Wu, Ben-Lai Zhang, Hong-Yun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Fe(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], the Fe(II) atom is located on a twofold rotation axis and is coordinated by two trans-positioned N,O-bidentate and zwitterionic 5-carboxy-2-(pyridinium-4-yl)-1H-imidazol-1-ide-4-carboxylate H(2)PIDC(−) ligands and two water mol­ecules in a distorted environment. In the crystal packing, a three-dimensional network is constructed via hydrogen-bonding involving the water mol­ecules, uncoordinated imidazole N atom, protonated pyridine N and carboxyl­ate O atoms. International Union of Crystallography 2009-06-24 /pmc/articles/PMC2969200/ /pubmed/21582742 http://dx.doi.org/10.1107/S160053680902337X Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Xia
Liu, Wei
Wu, Ben-Lai
Zhang, Hong-Yun
trans-Diaqua­bis[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ido-κ(2) N (3),O (4)]iron(II)
title trans-Diaqua­bis[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ido-κ(2) N (3),O (4)]iron(II)
title_full trans-Diaqua­bis[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ido-κ(2) N (3),O (4)]iron(II)
title_fullStr trans-Diaqua­bis[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ido-κ(2) N (3),O (4)]iron(II)
title_full_unstemmed trans-Diaqua­bis[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ido-κ(2) N (3),O (4)]iron(II)
title_short trans-Diaqua­bis[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1H-imidazol-1-ido-κ(2) N (3),O (4)]iron(II)
title_sort trans-diaqua­bis[5-carb­oxy-4-carboxyl­ato-2-(4-pyridinio)-1h-imidazol-1-ido-κ(2) n (3),o (4)]iron(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969200/
https://www.ncbi.nlm.nih.gov/pubmed/21582742
http://dx.doi.org/10.1107/S160053680902337X
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