(2-Carboxy­benzoato-κ(2) O (1),O (1′))(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N)nickel(II) perchlorate monohydrate

The title compound, [Ni(C(8)H(5)O(4))(C(16)H(36)N(4))]ClO(4)·H(2)O, has the Ni(II) atom in a distorted octa­hedral geometry, surrounded by coordination by four N atoms of the 5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane ligand in a folded configuration, and two carboxyl­ate O atom...

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Detalles Bibliográficos
Autores principales: Ou, Guang-Chuan, Zhang, Min, Yuan, Xian-You
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969201/
https://www.ncbi.nlm.nih.gov/pubmed/21582669
http://dx.doi.org/10.1107/S1600536809020169
Descripción
Sumario:The title compound, [Ni(C(8)H(5)O(4))(C(16)H(36)N(4))]ClO(4)·H(2)O, has the Ni(II) atom in a distorted octa­hedral geometry, surrounded by coordination by four N atoms of the 5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane ligand in a folded configuration, and two carboxyl­ate O atoms of the 2-carboxy­benzoate ligand in cis positions. The complex cation, the disordered perchlorate anion [occupancies 0.639 (8):0.361 (8)] and uncoordinated water mol­ecules engage in N—H⋯O and O—H⋯O hydrogen bonding, forming a layer structure parallel to (010).

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