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(2-Carboxybenzoato-κ(2) O (1),O (1′))(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4) N)nickel(II) perchlorate monohydrate
The title compound, [Ni(C(8)H(5)O(4))(C(16)H(36)N(4))]ClO(4)·H(2)O, has the Ni(II) atom in a distorted octahedral geometry, surrounded by coordination by four N atoms of the 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane ligand in a folded configuration, and two carboxylate O atom...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969201/ https://www.ncbi.nlm.nih.gov/pubmed/21582669 http://dx.doi.org/10.1107/S1600536809020169 |
| _version_ | 1782190073836470272 |
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| author | Ou, Guang-Chuan Zhang, Min Yuan, Xian-You |
| author_facet | Ou, Guang-Chuan Zhang, Min Yuan, Xian-You |
| author_sort | Ou, Guang-Chuan |
| collection | PubMed |
| description | The title compound, [Ni(C(8)H(5)O(4))(C(16)H(36)N(4))]ClO(4)·H(2)O, has the Ni(II) atom in a distorted octahedral geometry, surrounded by coordination by four N atoms of the 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane ligand in a folded configuration, and two carboxylate O atoms of the 2-carboxybenzoate ligand in cis positions. The complex cation, the disordered perchlorate anion [occupancies 0.639 (8):0.361 (8)] and uncoordinated water molecules engage in N—H⋯O and O—H⋯O hydrogen bonding, forming a layer structure parallel to (010). |
| format | Text |
| id | pubmed-2969201 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29692012010-12-30 (2-Carboxybenzoato-κ(2) O (1),O (1′))(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4) N)nickel(II) perchlorate monohydrate Ou, Guang-Chuan Zhang, Min Yuan, Xian-You Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(8)H(5)O(4))(C(16)H(36)N(4))]ClO(4)·H(2)O, has the Ni(II) atom in a distorted octahedral geometry, surrounded by coordination by four N atoms of the 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane ligand in a folded configuration, and two carboxylate O atoms of the 2-carboxybenzoate ligand in cis positions. The complex cation, the disordered perchlorate anion [occupancies 0.639 (8):0.361 (8)] and uncoordinated water molecules engage in N—H⋯O and O—H⋯O hydrogen bonding, forming a layer structure parallel to (010). International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969201/ /pubmed/21582669 http://dx.doi.org/10.1107/S1600536809020169 Text en © Ou et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ou, Guang-Chuan Zhang, Min Yuan, Xian-You (2-Carboxybenzoato-κ(2) O (1),O (1′))(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4) N)nickel(II) perchlorate monohydrate |
| title | (2-Carboxybenzoato-κ(2)
O
(1),O
(1′))(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N)nickel(II) perchlorate monohydrate |
| title_full | (2-Carboxybenzoato-κ(2)
O
(1),O
(1′))(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N)nickel(II) perchlorate monohydrate |
| title_fullStr | (2-Carboxybenzoato-κ(2)
O
(1),O
(1′))(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N)nickel(II) perchlorate monohydrate |
| title_full_unstemmed | (2-Carboxybenzoato-κ(2)
O
(1),O
(1′))(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N)nickel(II) perchlorate monohydrate |
| title_short | (2-Carboxybenzoato-κ(2)
O
(1),O
(1′))(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
N)nickel(II) perchlorate monohydrate |
| title_sort | (2-carboxybenzoato-κ(2)
o
(1),o
(1′))(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ(4)
n)nickel(ii) perchlorate monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969201/ https://www.ncbi.nlm.nih.gov/pubmed/21582669 http://dx.doi.org/10.1107/S1600536809020169 |
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