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(2-Amido-3-oxidopyridinium-κ(2) N,O)dibenzylchloridotin(IV)
The Sn atom in the title compound, [Sn(C(7)H(7))(2)(C(5)H(5)N(2)O)Cl], shows a distorted C(2)ClNOSn trigonal-bipyramidal coordination, with a Cl–Sn–O axial angle of 163.77 (3)°, but the C—Sn—C angle [141.43 (7)°] deviates from 120°. The chelating ligand exists in a zwitterionic form. Adjacent molec...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969204/ https://www.ncbi.nlm.nih.gov/pubmed/21582665 http://dx.doi.org/10.1107/S1600536809020339 |
| _version_ | 1782190074750828544 |
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| author | Tan, Chui Lian Lo, Kong Mun Ng, Seik Weng |
| author_facet | Tan, Chui Lian Lo, Kong Mun Ng, Seik Weng |
| author_sort | Tan, Chui Lian |
| collection | PubMed |
| description | The Sn atom in the title compound, [Sn(C(7)H(7))(2)(C(5)H(5)N(2)O)Cl], shows a distorted C(2)ClNOSn trigonal-bipyramidal coordination, with a Cl–Sn–O axial angle of 163.77 (3)°, but the C—Sn—C angle [141.43 (7)°] deviates from 120°. The chelating ligand exists in a zwitterionic form. Adjacent molecules are linked by an N—H(pyridinium)⋯O hydrogen bond, forming a chain running along the c axis of the orthorhombic unit cell. |
| format | Text |
| id | pubmed-2969204 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29692042010-12-30 (2-Amido-3-oxidopyridinium-κ(2) N,O)dibenzylchloridotin(IV) Tan, Chui Lian Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn atom in the title compound, [Sn(C(7)H(7))(2)(C(5)H(5)N(2)O)Cl], shows a distorted C(2)ClNOSn trigonal-bipyramidal coordination, with a Cl–Sn–O axial angle of 163.77 (3)°, but the C—Sn—C angle [141.43 (7)°] deviates from 120°. The chelating ligand exists in a zwitterionic form. Adjacent molecules are linked by an N—H(pyridinium)⋯O hydrogen bond, forming a chain running along the c axis of the orthorhombic unit cell. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969204/ /pubmed/21582665 http://dx.doi.org/10.1107/S1600536809020339 Text en © Tan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Tan, Chui Lian Lo, Kong Mun Ng, Seik Weng (2-Amido-3-oxidopyridinium-κ(2) N,O)dibenzylchloridotin(IV) |
| title | (2-Amido-3-oxidopyridinium-κ(2)
N,O)dibenzylchloridotin(IV) |
| title_full | (2-Amido-3-oxidopyridinium-κ(2)
N,O)dibenzylchloridotin(IV) |
| title_fullStr | (2-Amido-3-oxidopyridinium-κ(2)
N,O)dibenzylchloridotin(IV) |
| title_full_unstemmed | (2-Amido-3-oxidopyridinium-κ(2)
N,O)dibenzylchloridotin(IV) |
| title_short | (2-Amido-3-oxidopyridinium-κ(2)
N,O)dibenzylchloridotin(IV) |
| title_sort | (2-amido-3-oxidopyridinium-κ(2)
n,o)dibenzylchloridotin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969204/ https://www.ncbi.nlm.nih.gov/pubmed/21582665 http://dx.doi.org/10.1107/S1600536809020339 |
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