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(E)-1-(2-Thienyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one
The molecule of the title heteroaryl chalcone, C(16)H(16)O(4)S, which consists of substituted thiophene and benzene rings bridged by the prop-2-en-1-one group, is slightly twisted. The dihedral angle between the thiophene and 3,4,5-trimethoxyphenyl rings is 12.18 (4)°. The three methoxy groups...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969210/ https://www.ncbi.nlm.nih.gov/pubmed/21582853 http://dx.doi.org/10.1107/S1600536809021850 |
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author | Suwunwong, Thitipone Chantrapromma, Suchada Pakdeevanich, Paradorn Fun, Hoong-Kun |
author_facet | Suwunwong, Thitipone Chantrapromma, Suchada Pakdeevanich, Paradorn Fun, Hoong-Kun |
author_sort | Suwunwong, Thitipone |
collection | PubMed |
description | The molecule of the title heteroaryl chalcone, C(16)H(16)O(4)S, which consists of substituted thiophene and benzene rings bridged by the prop-2-en-1-one group, is slightly twisted. The dihedral angle between the thiophene and 3,4,5-trimethoxyphenyl rings is 12.18 (4)°. The three methoxy groups have two different conformations; two methoxy groups are coplanar [C—O—C—C torsion angles = −1.38 (12) and 0.47 (12)°] whereas the third is (-)-synclinal with the benzene ring. In the crystal structure, adjacent molecules are linked in a face-to-side manner into chains along the c axis by weak C—H⋯O(enone) interactions. These chains are stacked along the b axis by weak C—H⋯O(methoxy) interactions. |
format | Text |
id | pubmed-2969210 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29692102010-12-30 (E)-1-(2-Thienyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one Suwunwong, Thitipone Chantrapromma, Suchada Pakdeevanich, Paradorn Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title heteroaryl chalcone, C(16)H(16)O(4)S, which consists of substituted thiophene and benzene rings bridged by the prop-2-en-1-one group, is slightly twisted. The dihedral angle between the thiophene and 3,4,5-trimethoxyphenyl rings is 12.18 (4)°. The three methoxy groups have two different conformations; two methoxy groups are coplanar [C—O—C—C torsion angles = −1.38 (12) and 0.47 (12)°] whereas the third is (-)-synclinal with the benzene ring. In the crystal structure, adjacent molecules are linked in a face-to-side manner into chains along the c axis by weak C—H⋯O(enone) interactions. These chains are stacked along the b axis by weak C—H⋯O(methoxy) interactions. International Union of Crystallography 2009-06-13 /pmc/articles/PMC2969210/ /pubmed/21582853 http://dx.doi.org/10.1107/S1600536809021850 Text en © Suwunwong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Suwunwong, Thitipone Chantrapromma, Suchada Pakdeevanich, Paradorn Fun, Hoong-Kun (E)-1-(2-Thienyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one |
title | (E)-1-(2-Thienyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one
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title_full | (E)-1-(2-Thienyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one
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title_fullStr | (E)-1-(2-Thienyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one
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title_full_unstemmed | (E)-1-(2-Thienyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one
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title_short | (E)-1-(2-Thienyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one
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title_sort | (e)-1-(2-thienyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969210/ https://www.ncbi.nlm.nih.gov/pubmed/21582853 http://dx.doi.org/10.1107/S1600536809021850 |
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