(N (4)-n-Butyl­pyridine-4-carbothio­amide-κN (4))chloridobis(dimethyl­glyoximato-κ(2) N,N′)cobalt(III) hemihydrate

The title compound, trans-[Co(C(4)H(7)N(2)O(2))(2)Cl(C(10)H(14)N(2)S)]·0.5H(2)O, contains two independent mol­ecules in the asymmetric unit in which the Co(III) ions are coordinated in slightly distorted octa­hedral coordination environments. The bis-chelating glyoximate ligands, which occupy equato...

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Detalles Bibliográficos
Autores principales: Revathi, C., Dayalan, A., SethuSankar, K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969215/
https://www.ncbi.nlm.nih.gov/pubmed/21582722
http://dx.doi.org/10.1107/S1600536809022661
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author Revathi, C.
Dayalan, A.
SethuSankar, K.
author_facet Revathi, C.
Dayalan, A.
SethuSankar, K.
author_sort Revathi, C.
collection PubMed
description The title compound, trans-[Co(C(4)H(7)N(2)O(2))(2)Cl(C(10)H(14)N(2)S)]·0.5H(2)O, contains two independent mol­ecules in the asymmetric unit in which the Co(III) ions are coordinated in slightly distorted octa­hedral coordination environments. The bis-chelating glyoximate ligands, which occupy equatorial sites, are linked by interligand O—H⋯O hydrogen bonds. The dihedral angles between the mean planes of the glyoximate ligands in each mol­ecule are 2.07 (8) and 1.60 (1)°. The asymmetric unit contains a solvent water mol­ecule which is disordered over two sites with refined occupancies 0.64 (2) and 0.36 (2).
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spelling pubmed-29692152010-12-30 (N (4)-n-Butyl­pyridine-4-carbothio­amide-κN (4))chloridobis(dimethyl­glyoximato-κ(2) N,N′)cobalt(III) hemihydrate Revathi, C. Dayalan, A. SethuSankar, K. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, trans-[Co(C(4)H(7)N(2)O(2))(2)Cl(C(10)H(14)N(2)S)]·0.5H(2)O, contains two independent mol­ecules in the asymmetric unit in which the Co(III) ions are coordinated in slightly distorted octa­hedral coordination environments. The bis-chelating glyoximate ligands, which occupy equatorial sites, are linked by interligand O—H⋯O hydrogen bonds. The dihedral angles between the mean planes of the glyoximate ligands in each mol­ecule are 2.07 (8) and 1.60 (1)°. The asymmetric unit contains a solvent water mol­ecule which is disordered over two sites with refined occupancies 0.64 (2) and 0.36 (2). International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969215/ /pubmed/21582722 http://dx.doi.org/10.1107/S1600536809022661 Text en © Revathi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Revathi, C.
Dayalan, A.
SethuSankar, K.
(N (4)-n-Butyl­pyridine-4-carbothio­amide-κN (4))chloridobis(dimethyl­glyoximato-κ(2) N,N′)cobalt(III) hemihydrate
title (N (4)-n-Butyl­pyridine-4-carbothio­amide-κN (4))chloridobis(dimethyl­glyoximato-κ(2) N,N′)cobalt(III) hemihydrate
title_full (N (4)-n-Butyl­pyridine-4-carbothio­amide-κN (4))chloridobis(dimethyl­glyoximato-κ(2) N,N′)cobalt(III) hemihydrate
title_fullStr (N (4)-n-Butyl­pyridine-4-carbothio­amide-κN (4))chloridobis(dimethyl­glyoximato-κ(2) N,N′)cobalt(III) hemihydrate
title_full_unstemmed (N (4)-n-Butyl­pyridine-4-carbothio­amide-κN (4))chloridobis(dimethyl­glyoximato-κ(2) N,N′)cobalt(III) hemihydrate
title_short (N (4)-n-Butyl­pyridine-4-carbothio­amide-κN (4))chloridobis(dimethyl­glyoximato-κ(2) N,N′)cobalt(III) hemihydrate
title_sort (n (4)-n-butyl­pyridine-4-carbothio­amide-κn (4))chloridobis(dimethyl­glyoximato-κ(2) n,n′)cobalt(iii) hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969215/
https://www.ncbi.nlm.nih.gov/pubmed/21582722
http://dx.doi.org/10.1107/S1600536809022661
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AT sethusankark n4nbutylpyridine4carbothioamidekn4chloridobisdimethylglyoximatok2nncobaltiiihemihydrate

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