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4,8,9,10-Tetrakis(4-fluorophenyl)-1,3-diazatricyclo[3.3.1.1]decan-6-one
In the title compound, C(32)H(24)F(4)N(2)O, all four six-membered rings that constitute the diazaadamantanone cage adopt chair conformations. Two of the four fluorophenyl substituents occupy axial positions and the other two occupy equatorial positions relative to their respective C(5)N rings of t...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969218/ https://www.ncbi.nlm.nih.gov/pubmed/21582820 http://dx.doi.org/10.1107/S160053680902090X |
Sumario: | In the title compound, C(32)H(24)F(4)N(2)O, all four six-membered rings that constitute the diazaadamantanone cage adopt chair conformations. Two of the four fluorophenyl substituents occupy axial positions and the other two occupy equatorial positions relative to their respective C(5)N rings of the adamantane framework. The crystal structure is stabilized by C—H⋯O interactions, generating a C(5) chain along the a axis. |
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