4,8,9,10-Tetra­kis(4-fluoro­phen­yl)-1,3-diaza­tricyclo­[3.3.1.1]decan-6-one

In the title compound, C(32)H(24)F(4)N(2)O, all four six-membered rings that constitute the diaza­adamantanone cage adopt chair conformations. Two of the four fluoro­phenyl substituents occupy axial positions and the other two occupy equatorial positions relative to their respective C(5)N rings of t...

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Detalles Bibliográficos
Autores principales: Natarajan, S., Priya, V. Sudha, Vijayakumar, V., Suresh, J., Lakshman, P. L. Nilantha
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969218/
https://www.ncbi.nlm.nih.gov/pubmed/21582820
http://dx.doi.org/10.1107/S160053680902090X
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author Natarajan, S.
Priya, V. Sudha
Vijayakumar, V.
Suresh, J.
Lakshman, P. L. Nilantha
author_facet Natarajan, S.
Priya, V. Sudha
Vijayakumar, V.
Suresh, J.
Lakshman, P. L. Nilantha
author_sort Natarajan, S.
collection PubMed
description In the title compound, C(32)H(24)F(4)N(2)O, all four six-membered rings that constitute the diaza­adamantanone cage adopt chair conformations. Two of the four fluoro­phenyl substituents occupy axial positions and the other two occupy equatorial positions relative to their respective C(5)N rings of the adamantane framework. The crystal structure is stabilized by C—H⋯O inter­actions, generating a C(5) chain along the a axis.
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spelling pubmed-29692182010-12-30 4,8,9,10-Tetra­kis(4-fluoro­phen­yl)-1,3-diaza­tricyclo­[3.3.1.1]decan-6-one Natarajan, S. Priya, V. Sudha Vijayakumar, V. Suresh, J. Lakshman, P. L. Nilantha Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(32)H(24)F(4)N(2)O, all four six-membered rings that constitute the diaza­adamantanone cage adopt chair conformations. Two of the four fluoro­phenyl substituents occupy axial positions and the other two occupy equatorial positions relative to their respective C(5)N rings of the adamantane framework. The crystal structure is stabilized by C—H⋯O inter­actions, generating a C(5) chain along the a axis. International Union of Crystallography 2009-06-10 /pmc/articles/PMC2969218/ /pubmed/21582820 http://dx.doi.org/10.1107/S160053680902090X Text en © Natarajan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Natarajan, S.
Priya, V. Sudha
Vijayakumar, V.
Suresh, J.
Lakshman, P. L. Nilantha
4,8,9,10-Tetra­kis(4-fluoro­phen­yl)-1,3-diaza­tricyclo­[3.3.1.1]decan-6-one
title 4,8,9,10-Tetra­kis(4-fluoro­phen­yl)-1,3-diaza­tricyclo­[3.3.1.1]decan-6-one
title_full 4,8,9,10-Tetra­kis(4-fluoro­phen­yl)-1,3-diaza­tricyclo­[3.3.1.1]decan-6-one
title_fullStr 4,8,9,10-Tetra­kis(4-fluoro­phen­yl)-1,3-diaza­tricyclo­[3.3.1.1]decan-6-one
title_full_unstemmed 4,8,9,10-Tetra­kis(4-fluoro­phen­yl)-1,3-diaza­tricyclo­[3.3.1.1]decan-6-one
title_short 4,8,9,10-Tetra­kis(4-fluoro­phen­yl)-1,3-diaza­tricyclo­[3.3.1.1]decan-6-one
title_sort 4,8,9,10-tetra­kis(4-fluoro­phen­yl)-1,3-diaza­tricyclo­[3.3.1.1]decan-6-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969218/
https://www.ncbi.nlm.nih.gov/pubmed/21582820
http://dx.doi.org/10.1107/S160053680902090X
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