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Hydroxonium creatininium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cobaltate(II) trihydrate
The title compound, (C(4)H(8)N(3)O)(H(3)O)[Co(C(7)H(3)NO(4))(2)]·3H(2)O, contains a protonated creatininium cation, a hydroxonium (H(3)O)(+) cation, a [Co(pydc)(2)](2−) (pydcH(2) = pyridine-2,6-dicarboxylic acid) complex anion, and three uncoordinated water molecules. The Co(II) atom is coordinate...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969222/ https://www.ncbi.nlm.nih.gov/pubmed/21582745 http://dx.doi.org/10.1107/S1600536809021837 |
| _version_ | 1782190080517996544 |
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| author | Aghabozorg, Hossein Derikvand, Zohreh Attar Gharamaleki, Jafar Yousefi, Mohammad |
| author_facet | Aghabozorg, Hossein Derikvand, Zohreh Attar Gharamaleki, Jafar Yousefi, Mohammad |
| author_sort | Aghabozorg, Hossein |
| collection | PubMed |
| description | The title compound, (C(4)H(8)N(3)O)(H(3)O)[Co(C(7)H(3)NO(4))(2)]·3H(2)O, contains a protonated creatininium cation, a hydroxonium (H(3)O)(+) cation, a [Co(pydc)(2)](2−) (pydcH(2) = pyridine-2,6-dicarboxylic acid) complex anion, and three uncoordinated water molecules. The Co(II) atom is coordinated by four O and two N atoms from two pydc ligands in a distorted octahedral environment. The structure also contains three uncoordinated water molecules. Extensive intermolecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, π–π stacking interactions [centroid–centroid distances = 3.565 (14) and 3.425 (14) Å] and O⋯π interactions [O⋯centroid distance = 3.480 (2) Å] connect the various components in the crystal structure. |
| format | Text |
| id | pubmed-2969222 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29692222010-12-30 Hydroxonium creatininium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cobaltate(II) trihydrate Aghabozorg, Hossein Derikvand, Zohreh Attar Gharamaleki, Jafar Yousefi, Mohammad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(4)H(8)N(3)O)(H(3)O)[Co(C(7)H(3)NO(4))(2)]·3H(2)O, contains a protonated creatininium cation, a hydroxonium (H(3)O)(+) cation, a [Co(pydc)(2)](2−) (pydcH(2) = pyridine-2,6-dicarboxylic acid) complex anion, and three uncoordinated water molecules. The Co(II) atom is coordinated by four O and two N atoms from two pydc ligands in a distorted octahedral environment. The structure also contains three uncoordinated water molecules. Extensive intermolecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, π–π stacking interactions [centroid–centroid distances = 3.565 (14) and 3.425 (14) Å] and O⋯π interactions [O⋯centroid distance = 3.480 (2) Å] connect the various components in the crystal structure. International Union of Crystallography 2009-06-27 /pmc/articles/PMC2969222/ /pubmed/21582745 http://dx.doi.org/10.1107/S1600536809021837 Text en © Aghabozorg et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Aghabozorg, Hossein Derikvand, Zohreh Attar Gharamaleki, Jafar Yousefi, Mohammad Hydroxonium creatininium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cobaltate(II) trihydrate |
| title | Hydroxonium creatininium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cobaltate(II) trihydrate |
| title_full | Hydroxonium creatininium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cobaltate(II) trihydrate |
| title_fullStr | Hydroxonium creatininium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cobaltate(II) trihydrate |
| title_full_unstemmed | Hydroxonium creatininium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cobaltate(II) trihydrate |
| title_short | Hydroxonium creatininium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cobaltate(II) trihydrate |
| title_sort | hydroxonium creatininium bis(pyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))cobaltate(ii) trihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969222/ https://www.ncbi.nlm.nih.gov/pubmed/21582745 http://dx.doi.org/10.1107/S1600536809021837 |
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