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[N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ(2) N′,O]dimethyltin(IV)
The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(18)H(11)ClN(2)O(3))], shows a trans-C(2)NO(2)Sn trigonal-bipyramidal coordination; the axial O—Sn—O angle is 155.22 (5)°. The tridentate N′-(5-chloro-2-oxidobenzylidene)-3-hydroxy-2-naphthohydrazidate dianion is stabilized by an intramolecul...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969223/ https://www.ncbi.nlm.nih.gov/pubmed/21582739 http://dx.doi.org/10.1107/S1600536809022259 |
| _version_ | 1782190080759169024 |
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| author | Lee, See Mun Lo, Kong Mun Mohd Ali, Hapipah Ng, Seik Weng |
| author_facet | Lee, See Mun Lo, Kong Mun Mohd Ali, Hapipah Ng, Seik Weng |
| author_sort | Lee, See Mun |
| collection | PubMed |
| description | The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(18)H(11)ClN(2)O(3))], shows a trans-C(2)NO(2)Sn trigonal-bipyramidal coordination; the axial O—Sn—O angle is 155.22 (5)°. The tridentate N′-(5-chloro-2-oxidobenzylidene)-3-hydroxy-2-naphthohydrazidate dianion is stabilized by an intramolecular O—H⋯N hydrogen bond. |
| format | Text |
| id | pubmed-2969223 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29692232010-12-30 [N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ(2) N′,O]dimethyltin(IV) Lee, See Mun Lo, Kong Mun Mohd Ali, Hapipah Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(18)H(11)ClN(2)O(3))], shows a trans-C(2)NO(2)Sn trigonal-bipyramidal coordination; the axial O—Sn—O angle is 155.22 (5)°. The tridentate N′-(5-chloro-2-oxidobenzylidene)-3-hydroxy-2-naphthohydrazidate dianion is stabilized by an intramolecular O—H⋯N hydrogen bond. International Union of Crystallography 2009-06-24 /pmc/articles/PMC2969223/ /pubmed/21582739 http://dx.doi.org/10.1107/S1600536809022259 Text en © Lee et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lee, See Mun Lo, Kong Mun Mohd Ali, Hapipah Ng, Seik Weng [N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ(2) N′,O]dimethyltin(IV) |
| title | [N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ(2)
N′,O]dimethyltin(IV) |
| title_full | [N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ(2)
N′,O]dimethyltin(IV) |
| title_fullStr | [N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ(2)
N′,O]dimethyltin(IV) |
| title_full_unstemmed | [N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ(2)
N′,O]dimethyltin(IV) |
| title_short | [N′-(5-Chloro-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ(2)
N′,O]dimethyltin(IV) |
| title_sort | [n′-(5-chloro-2-oxidobenzylidene-κo)-3-hydroxy-2-naphthohydrazidato-κ(2)
n′,o]dimethyltin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969223/ https://www.ncbi.nlm.nih.gov/pubmed/21582739 http://dx.doi.org/10.1107/S1600536809022259 |
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