4,4′-Dianilino-3,3′-(4-chloro­benzyl­idene)bis­[furan-2(5H)-one]

In the mol­ecule of the title compound, C(27)H(21)ClN(2)O(4), the dihedral angle between the furan rings is 67.00 (3)°. The chloro­phenyl ring is oriented at dihedral angles of 76.61 (3) and 69.36 (3)° with respect to the furan rings. An intra­molecular N—H⋯O inter­action results in the formation of...

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Detalles Bibliográficos
Autores principales: Shi, Feng, Zhou, Dian-Xiang, Tu, Shu-Jiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969224/
https://www.ncbi.nlm.nih.gov/pubmed/21582807
http://dx.doi.org/10.1107/S1600536809021084
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author Shi, Feng
Zhou, Dian-Xiang
Tu, Shu-Jiang
author_facet Shi, Feng
Zhou, Dian-Xiang
Tu, Shu-Jiang
author_sort Shi, Feng
collection PubMed
description In the mol­ecule of the title compound, C(27)H(21)ClN(2)O(4), the dihedral angle between the furan rings is 67.00 (3)°. The chloro­phenyl ring is oriented at dihedral angles of 76.61 (3) and 69.36 (3)° with respect to the furan rings. An intra­molecular N—H⋯O inter­action results in the formation of an eight-membered ring with a twisted conformation. In the crystal structure, inter­molecular N—H⋯O and C—H⋯O inter­actions link the mol­ecules into a three-dimensional network, forming R (2) (2)(16) ring motifs. Three weak C—H⋯π inter­actions are also found.
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spelling pubmed-29692242010-12-30 4,4′-Dianilino-3,3′-(4-chloro­benzyl­idene)bis­[furan-2(5H)-one] Shi, Feng Zhou, Dian-Xiang Tu, Shu-Jiang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(27)H(21)ClN(2)O(4), the dihedral angle between the furan rings is 67.00 (3)°. The chloro­phenyl ring is oriented at dihedral angles of 76.61 (3) and 69.36 (3)° with respect to the furan rings. An intra­molecular N—H⋯O inter­action results in the formation of an eight-membered ring with a twisted conformation. In the crystal structure, inter­molecular N—H⋯O and C—H⋯O inter­actions link the mol­ecules into a three-dimensional network, forming R (2) (2)(16) ring motifs. Three weak C—H⋯π inter­actions are also found. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969224/ /pubmed/21582807 http://dx.doi.org/10.1107/S1600536809021084 Text en © Shi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shi, Feng
Zhou, Dian-Xiang
Tu, Shu-Jiang
4,4′-Dianilino-3,3′-(4-chloro­benzyl­idene)bis­[furan-2(5H)-one]
title 4,4′-Dianilino-3,3′-(4-chloro­benzyl­idene)bis­[furan-2(5H)-one]
title_full 4,4′-Dianilino-3,3′-(4-chloro­benzyl­idene)bis­[furan-2(5H)-one]
title_fullStr 4,4′-Dianilino-3,3′-(4-chloro­benzyl­idene)bis­[furan-2(5H)-one]
title_full_unstemmed 4,4′-Dianilino-3,3′-(4-chloro­benzyl­idene)bis­[furan-2(5H)-one]
title_short 4,4′-Dianilino-3,3′-(4-chloro­benzyl­idene)bis­[furan-2(5H)-one]
title_sort 4,4′-dianilino-3,3′-(4-chloro­benzyl­idene)bis­[furan-2(5h)-one]
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969224/
https://www.ncbi.nlm.nih.gov/pubmed/21582807
http://dx.doi.org/10.1107/S1600536809021084
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