(3R,4R)-2,5-Dioxo-1-m-tolyl-3,4-diyl diacetate

In the enanti­omerically pure title compound, C(15)H(15)NO(6), the five-membered ring displays a twist conformation with the local axis through the N atom. The acetyl groups are perpendicular to the ring [dihedral angles 80.3 (1) and 89.3 (1)°] and project to opposite sides. The packing is governed...

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Detalles Bibliográficos
Autores principales: Naz, Sara, Zaidi, Javid, Mehmood, Tahir, Jones, Peter G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969227/
https://www.ncbi.nlm.nih.gov/pubmed/21582788
http://dx.doi.org/10.1107/S1600536809020637
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author Naz, Sara
Zaidi, Javid
Mehmood, Tahir
Jones, Peter G.
author_facet Naz, Sara
Zaidi, Javid
Mehmood, Tahir
Jones, Peter G.
author_sort Naz, Sara
collection PubMed
description In the enanti­omerically pure title compound, C(15)H(15)NO(6), the five-membered ring displays a twist conformation with the local axis through the N atom. The acetyl groups are perpendicular to the ring [dihedral angles 80.3 (1) and 89.3 (1)°] and project to opposite sides. The packing is governed by two weak C—H⋯O inter­actions, forming layers of mol­ecules parallel to the ab plane.
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spelling pubmed-29692272010-12-30 (3R,4R)-2,5-Dioxo-1-m-tolyl-3,4-diyl diacetate Naz, Sara Zaidi, Javid Mehmood, Tahir Jones, Peter G. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the enanti­omerically pure title compound, C(15)H(15)NO(6), the five-membered ring displays a twist conformation with the local axis through the N atom. The acetyl groups are perpendicular to the ring [dihedral angles 80.3 (1) and 89.3 (1)°] and project to opposite sides. The packing is governed by two weak C—H⋯O inter­actions, forming layers of mol­ecules parallel to the ab plane. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969227/ /pubmed/21582788 http://dx.doi.org/10.1107/S1600536809020637 Text en © Naz et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Naz, Sara
Zaidi, Javid
Mehmood, Tahir
Jones, Peter G.
(3R,4R)-2,5-Dioxo-1-m-tolyl-3,4-diyl diacetate
title (3R,4R)-2,5-Dioxo-1-m-tolyl-3,4-diyl diacetate
title_full (3R,4R)-2,5-Dioxo-1-m-tolyl-3,4-diyl diacetate
title_fullStr (3R,4R)-2,5-Dioxo-1-m-tolyl-3,4-diyl diacetate
title_full_unstemmed (3R,4R)-2,5-Dioxo-1-m-tolyl-3,4-diyl diacetate
title_short (3R,4R)-2,5-Dioxo-1-m-tolyl-3,4-diyl diacetate
title_sort (3r,4r)-2,5-dioxo-1-m-tolyl-3,4-diyl diacetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969227/
https://www.ncbi.nlm.nih.gov/pubmed/21582788
http://dx.doi.org/10.1107/S1600536809020637
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AT mehmoodtahir 3r4r25dioxo1mtolyl34diyldiacetate
AT jonespeterg 3r4r25dioxo1mtolyl34diyldiacetate

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