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catena-Poly[[[tetra­aqua­zinc(II)]-μ-4,4′-bipyridine-κ(2) N:N′] benzene-1,4-di­carboxyl­ate]

In the title compound, {[Zn(C(10)H(8)N(2))(H(2)O)(4)](C(8)H(4)O(4))}(n), the Zn(II) atoms, lying on a twofold rotation axis, are bridged by 4,4′-bipyridine ligands, resulting in a linear chain along the b axis. In the chain, the Zn(II) atom adopts a slightly distorted octa­hedral coordination geomet...

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Detalles Bibliográficos
Autores principales: Ruan, Ming-Bo, Deng, Jian-Cheng, Li, Zhi-Gang, Xu, Jing-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969229/
https://www.ncbi.nlm.nih.gov/pubmed/21582682
http://dx.doi.org/10.1107/S1600536809019412
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author Ruan, Ming-Bo
Deng, Jian-Cheng
Li, Zhi-Gang
Xu, Jing-Wei
author_facet Ruan, Ming-Bo
Deng, Jian-Cheng
Li, Zhi-Gang
Xu, Jing-Wei
author_sort Ruan, Ming-Bo
collection PubMed
description In the title compound, {[Zn(C(10)H(8)N(2))(H(2)O)(4)](C(8)H(4)O(4))}(n), the Zn(II) atoms, lying on a twofold rotation axis, are bridged by 4,4′-bipyridine ligands, resulting in a linear chain along the b axis. In the chain, the Zn(II) atom adopts a slightly distorted octa­hedral coordination geometry involving four water mol­ecules at the equatorial positions. The noncoordinated benzene-1,4-dicarboxyl­ate anion, which is also located on a twofold rotation axis, bridges adjacent chains through O—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network.
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spelling pubmed-29692292010-12-30 catena-Poly[[[tetra­aqua­zinc(II)]-μ-4,4′-bipyridine-κ(2) N:N′] benzene-1,4-di­carboxyl­ate] Ruan, Ming-Bo Deng, Jian-Cheng Li, Zhi-Gang Xu, Jing-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(C(10)H(8)N(2))(H(2)O)(4)](C(8)H(4)O(4))}(n), the Zn(II) atoms, lying on a twofold rotation axis, are bridged by 4,4′-bipyridine ligands, resulting in a linear chain along the b axis. In the chain, the Zn(II) atom adopts a slightly distorted octa­hedral coordination geometry involving four water mol­ecules at the equatorial positions. The noncoordinated benzene-1,4-dicarboxyl­ate anion, which is also located on a twofold rotation axis, bridges adjacent chains through O—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969229/ /pubmed/21582682 http://dx.doi.org/10.1107/S1600536809019412 Text en © Ruan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ruan, Ming-Bo
Deng, Jian-Cheng
Li, Zhi-Gang
Xu, Jing-Wei
catena-Poly[[[tetra­aqua­zinc(II)]-μ-4,4′-bipyridine-κ(2) N:N′] benzene-1,4-di­carboxyl­ate]
title catena-Poly[[[tetra­aqua­zinc(II)]-μ-4,4′-bipyridine-κ(2) N:N′] benzene-1,4-di­carboxyl­ate]
title_full catena-Poly[[[tetra­aqua­zinc(II)]-μ-4,4′-bipyridine-κ(2) N:N′] benzene-1,4-di­carboxyl­ate]
title_fullStr catena-Poly[[[tetra­aqua­zinc(II)]-μ-4,4′-bipyridine-κ(2) N:N′] benzene-1,4-di­carboxyl­ate]
title_full_unstemmed catena-Poly[[[tetra­aqua­zinc(II)]-μ-4,4′-bipyridine-κ(2) N:N′] benzene-1,4-di­carboxyl­ate]
title_short catena-Poly[[[tetra­aqua­zinc(II)]-μ-4,4′-bipyridine-κ(2) N:N′] benzene-1,4-di­carboxyl­ate]
title_sort catena-poly[[[tetra­aqua­zinc(ii)]-μ-4,4′-bipyridine-κ(2) n:n′] benzene-1,4-di­carboxyl­ate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969229/
https://www.ncbi.nlm.nih.gov/pubmed/21582682
http://dx.doi.org/10.1107/S1600536809019412
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