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catena-Poly[[[tetraaquazinc(II)]-μ-4,4′-bipyridine-κ(2) N:N′] benzene-1,4-dicarboxylate]
In the title compound, {[Zn(C(10)H(8)N(2))(H(2)O)(4)](C(8)H(4)O(4))}(n), the Zn(II) atoms, lying on a twofold rotation axis, are bridged by 4,4′-bipyridine ligands, resulting in a linear chain along the b axis. In the chain, the Zn(II) atom adopts a slightly distorted octahedral coordination geomet...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969229/ https://www.ncbi.nlm.nih.gov/pubmed/21582682 http://dx.doi.org/10.1107/S1600536809019412 |
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author | Ruan, Ming-Bo Deng, Jian-Cheng Li, Zhi-Gang Xu, Jing-Wei |
author_facet | Ruan, Ming-Bo Deng, Jian-Cheng Li, Zhi-Gang Xu, Jing-Wei |
author_sort | Ruan, Ming-Bo |
collection | PubMed |
description | In the title compound, {[Zn(C(10)H(8)N(2))(H(2)O)(4)](C(8)H(4)O(4))}(n), the Zn(II) atoms, lying on a twofold rotation axis, are bridged by 4,4′-bipyridine ligands, resulting in a linear chain along the b axis. In the chain, the Zn(II) atom adopts a slightly distorted octahedral coordination geometry involving four water molecules at the equatorial positions. The noncoordinated benzene-1,4-dicarboxylate anion, which is also located on a twofold rotation axis, bridges adjacent chains through O—H⋯O hydrogen bonds, forming a three-dimensional supramolecular network. |
format | Text |
id | pubmed-2969229 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29692292010-12-30 catena-Poly[[[tetraaquazinc(II)]-μ-4,4′-bipyridine-κ(2) N:N′] benzene-1,4-dicarboxylate] Ruan, Ming-Bo Deng, Jian-Cheng Li, Zhi-Gang Xu, Jing-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(C(10)H(8)N(2))(H(2)O)(4)](C(8)H(4)O(4))}(n), the Zn(II) atoms, lying on a twofold rotation axis, are bridged by 4,4′-bipyridine ligands, resulting in a linear chain along the b axis. In the chain, the Zn(II) atom adopts a slightly distorted octahedral coordination geometry involving four water molecules at the equatorial positions. The noncoordinated benzene-1,4-dicarboxylate anion, which is also located on a twofold rotation axis, bridges adjacent chains through O—H⋯O hydrogen bonds, forming a three-dimensional supramolecular network. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969229/ /pubmed/21582682 http://dx.doi.org/10.1107/S1600536809019412 Text en © Ruan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ruan, Ming-Bo Deng, Jian-Cheng Li, Zhi-Gang Xu, Jing-Wei catena-Poly[[[tetraaquazinc(II)]-μ-4,4′-bipyridine-κ(2) N:N′] benzene-1,4-dicarboxylate] |
title |
catena-Poly[[[tetraaquazinc(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] benzene-1,4-dicarboxylate] |
title_full |
catena-Poly[[[tetraaquazinc(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] benzene-1,4-dicarboxylate] |
title_fullStr |
catena-Poly[[[tetraaquazinc(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] benzene-1,4-dicarboxylate] |
title_full_unstemmed |
catena-Poly[[[tetraaquazinc(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] benzene-1,4-dicarboxylate] |
title_short |
catena-Poly[[[tetraaquazinc(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] benzene-1,4-dicarboxylate] |
title_sort | catena-poly[[[tetraaquazinc(ii)]-μ-4,4′-bipyridine-κ(2)
n:n′] benzene-1,4-dicarboxylate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969229/ https://www.ncbi.nlm.nih.gov/pubmed/21582682 http://dx.doi.org/10.1107/S1600536809019412 |
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