(4′-Ferrocenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(1,10-phenanthroline-κ(2) N,N′)copper(II) bis(perchlorate) acetonitrile solvate

The title complex, [CuFe(C(5)H(5))(C(20)H(14)N(3))(C(12)H(8)N(2))](ClO(4))(2)·C(2)H(3)N, consists of a mononuclear [Cu(C(12)H(8)N(2))(C(25)H(19)FeN(3))](2+) cation, two ClO(4) (−) anions (one of which is disordered over two positions with equal occupancy) and one CH(3)CN solvent mol­ecule. The Cu(II) center has a distorted square-pyramidal coordination with three N atoms of the 4′-ferrocenyl-2,2′:6′,2′′- terpyridine (fctpy) ligand and one 1,10-phenanthroline (phen) N atom in the basal plane and a second phen N atom in the apical position with an axial distance of 2.254 (4) Å. The disordered ClO(4) (−) anion is weakly coordin­ated to the Cu(II) ion with a Cu—O distance of 2.766 (11) Å. The two cyclo­penta­dienyl rings of the ferrocenyl group are almost eclipsed with a deviation of 4.7 (1) °, and are involved in inter­molecular π–π inter­actions with the outer pyridyl rings of the fctpy ligands [centroid–centroid distance = 3.759 (2) Å.].