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(2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)bis(thiocyanato-κS)mercury(II)
In the molecule of the title compound, [Hg(NCS)(2)(C(26)H(20)N(2))], the Hg(II) atom is four-coordinated in a distorted tetrahedral configuration by two N atoms from a chelating 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligand and by two S atoms from two thiocyanate anions. The ligand ring sy...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969232/ https://www.ncbi.nlm.nih.gov/pubmed/21582740 http://dx.doi.org/10.1107/S1600536809023228 |
Sumario: | In the molecule of the title compound, [Hg(NCS)(2)(C(26)H(20)N(2))], the Hg(II) atom is four-coordinated in a distorted tetrahedral configuration by two N atoms from a chelating 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligand and by two S atoms from two thiocyanate anions. The ligand ring system is not planar. The dihedral angle between the phenyl rings is 53.20 (3)° . In the crystal structure, π–π contacts between phenanthroline rings [centroid–centroid distance = 3.981 (1) Å] may stabilize the structure. |
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