(2,9-Dimethyl-4,7-diphenyl-1,10-phen­anthroline-κ(2) N,N′)bis­(thio­cyanato-κS)mercury(II)

In the mol­ecule of the title compound, [Hg(NCS)(2)(C(26)H(20)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from a chelating 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligand and by two S atoms from two thio­cyanate anions. The ligand ring sy...

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Detalles Bibliográficos
Autor principal: Alizadeh, Robabeh
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969232/
https://www.ncbi.nlm.nih.gov/pubmed/21582740
http://dx.doi.org/10.1107/S1600536809023228
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author Alizadeh, Robabeh
author_facet Alizadeh, Robabeh
author_sort Alizadeh, Robabeh
collection PubMed
description In the mol­ecule of the title compound, [Hg(NCS)(2)(C(26)H(20)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from a chelating 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligand and by two S atoms from two thio­cyanate anions. The ligand ring system is not planar. The dihedral angle between the phenyl rings is 53.20 (3)° . In the crystal structure, π–π contacts between phenanthroline rings [centroid–centroid distance = 3.981 (1) Å] may stabilize the structure.
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spelling pubmed-29692322010-12-30 (2,9-Dimethyl-4,7-diphenyl-1,10-phen­anthroline-κ(2) N,N′)bis­(thio­cyanato-κS)mercury(II) Alizadeh, Robabeh Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mol­ecule of the title compound, [Hg(NCS)(2)(C(26)H(20)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from a chelating 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligand and by two S atoms from two thio­cyanate anions. The ligand ring system is not planar. The dihedral angle between the phenyl rings is 53.20 (3)° . In the crystal structure, π–π contacts between phenanthroline rings [centroid–centroid distance = 3.981 (1) Å] may stabilize the structure. International Union of Crystallography 2009-06-24 /pmc/articles/PMC2969232/ /pubmed/21582740 http://dx.doi.org/10.1107/S1600536809023228 Text en © Robabeh Alizadeh 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Alizadeh, Robabeh
(2,9-Dimethyl-4,7-diphenyl-1,10-phen­anthroline-κ(2) N,N′)bis­(thio­cyanato-κS)mercury(II)
title (2,9-Dimethyl-4,7-diphenyl-1,10-phen­anthroline-κ(2) N,N′)bis­(thio­cyanato-κS)mercury(II)
title_full (2,9-Dimethyl-4,7-diphenyl-1,10-phen­anthroline-κ(2) N,N′)bis­(thio­cyanato-κS)mercury(II)
title_fullStr (2,9-Dimethyl-4,7-diphenyl-1,10-phen­anthroline-κ(2) N,N′)bis­(thio­cyanato-κS)mercury(II)
title_full_unstemmed (2,9-Dimethyl-4,7-diphenyl-1,10-phen­anthroline-κ(2) N,N′)bis­(thio­cyanato-κS)mercury(II)
title_short (2,9-Dimethyl-4,7-diphenyl-1,10-phen­anthroline-κ(2) N,N′)bis­(thio­cyanato-κS)mercury(II)
title_sort (2,9-dimethyl-4,7-diphenyl-1,10-phen­anthroline-κ(2) n,n′)bis­(thio­cyanato-κs)mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969232/
https://www.ncbi.nlm.nih.gov/pubmed/21582740
http://dx.doi.org/10.1107/S1600536809023228
work_keys_str_mv AT alizadehrobabeh 29dimethyl47diphenyl110phenanthrolinek2nnbisthiocyanatoksmercuryii

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