(E)-1-(4-Fluoro­phen­yl)ethan-1-one semicarbazone

In the title compound, C(9)H(10)FN(3)O, the semicarbazone group is nearly planar, with the maximum deviation of 0.044 (1) Å for one of the N atoms. The mean plane of semicarbazone group forms a dihedral angle of 30.94 (4)° with the benzene ring. The mol­ecules are linked into a supra­molecular chain...

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Autores principales: Fun, Hoong-Kun, Yeap, Chin Sing, Padaki, Mahesh, Malladi, Shridhar, Isloor, Arun M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969237/
https://www.ncbi.nlm.nih.gov/pubmed/21582889
http://dx.doi.org/10.1107/S1600536809022521
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author Fun, Hoong-Kun
Yeap, Chin Sing
Padaki, Mahesh
Malladi, Shridhar
Isloor, Arun M.
author_facet Fun, Hoong-Kun
Yeap, Chin Sing
Padaki, Mahesh
Malladi, Shridhar
Isloor, Arun M.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(9)H(10)FN(3)O, the semicarbazone group is nearly planar, with the maximum deviation of 0.044 (1) Å for one of the N atoms. The mean plane of semicarbazone group forms a dihedral angle of 30.94 (4)° with the benzene ring. The mol­ecules are linked into a supra­molecular chain by N—H⋯O hydrogen bonds formed along the c axis. The crystal structure is further stabilized by weak inter­molucular C—H⋯π inter­actions; the closest C⋯Cg contact is 3.6505 (11) Å.
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spelling pubmed-29692372010-12-30 (E)-1-(4-Fluoro­phen­yl)ethan-1-one semicarbazone Fun, Hoong-Kun Yeap, Chin Sing Padaki, Mahesh Malladi, Shridhar Isloor, Arun M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(10)FN(3)O, the semicarbazone group is nearly planar, with the maximum deviation of 0.044 (1) Å for one of the N atoms. The mean plane of semicarbazone group forms a dihedral angle of 30.94 (4)° with the benzene ring. The mol­ecules are linked into a supra­molecular chain by N—H⋯O hydrogen bonds formed along the c axis. The crystal structure is further stabilized by weak inter­molucular C—H⋯π inter­actions; the closest C⋯Cg contact is 3.6505 (11) Å. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969237/ /pubmed/21582889 http://dx.doi.org/10.1107/S1600536809022521 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Yeap, Chin Sing
Padaki, Mahesh
Malladi, Shridhar
Isloor, Arun M.
(E)-1-(4-Fluoro­phen­yl)ethan-1-one semicarbazone
title (E)-1-(4-Fluoro­phen­yl)ethan-1-one semicarbazone
title_full (E)-1-(4-Fluoro­phen­yl)ethan-1-one semicarbazone
title_fullStr (E)-1-(4-Fluoro­phen­yl)ethan-1-one semicarbazone
title_full_unstemmed (E)-1-(4-Fluoro­phen­yl)ethan-1-one semicarbazone
title_short (E)-1-(4-Fluoro­phen­yl)ethan-1-one semicarbazone
title_sort (e)-1-(4-fluoro­phen­yl)ethan-1-one semicarbazone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969237/
https://www.ncbi.nlm.nih.gov/pubmed/21582889
http://dx.doi.org/10.1107/S1600536809022521
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AT isloorarunm e14fluorophenylethan1onesemicarbazone

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